Formation of Active Structures in Monolith Copper–Manganese Oxide Catalysts for Air-Heating Devices | Sciact - CRIS-system of Boreskov Institute of Catalysis

Formation of Active Structures in Monolith Copper–Manganese Oxide Catalysts for Air-Heating Devices Full article

Conference

III Российский конгресс по катализу «РОСКАТАЛИЗ»
22-26 May 2017 , Нижний Новгород

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 2018, Volume: 59, Number: 4, Pages: 532-543 Pages count : 12 DOI: 10.1134/s0023158418040122

Tags

catalyst, monolith support, butane oxidation, CuO, MnOx

Authors

Shikina N.V. ¹ , Yashnik S.A. ¹ , Gavrilova A.A. ¹ , Dovlitova L.S. ¹ , Khairulin S.R. ¹ , Kozlova G.S. ² , Ismagilov Z.R. ^1,3

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Center for Collective Use, Federal Research Center for Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences, Kemerovo, 650000 Russia
3	Institute of Coal Chemistry and Chemical Materials Science, Federal Research Center for Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences, Kemerovo, 650000 Russia

Funding (1)

Russian Foundation for Basic Research

17-43-540747

Impregnation catalysts based on CuO, MnOx, and CuO–MnOx with different Cu/Mn ratios supported on ceramic monoliths of alumina and silica are studied by BET, mercury porosimetry, X-ray diffraction analysis, transmission and scanning electron microscopy, temperature-programmed reduction with H2, diffuse reflectance electron spectroscopy, and differential dissolution. It is found that, in the butane oxidation reaction, CuO–MnOx catalysts exert a synergistic effect, which is attributed to the formation of highly defective phases of complex oxides of the nonstoichiometric spinel type with a large number of interparticle boundaries in the near-surface layers of the support.

Shikina N.V. , Yashnik S.A. , Gavrilova A.A. , Dovlitova L.S. , Khairulin S.R. , Kozlova G.S. , Ismagilov Z.R.
Formation of Active Structures in Monolith Copper–Manganese Oxide Catalysts for Air-Heating Devices
Kinetics and Catalysis. 2018. V.59. N4. P.532-543. DOI: 10.1134/s0023158418040122 WOS Scopus РИНЦ AN OpenAlex

Шикина Н.В. , Яшник С.А. , Гаврилова А.А. , Довлитова Л.С. , Хайрулин С.Р. , Козлова Г.С. , Исмагилов З.Р.
Формирование активных структур в блочных Cu−Mn-оксидных катализаторах для воздухонагревательных устройств
Кинетика и катализ. 2018. Т.59. №4. С.517-528. DOI: 10.1134/S0453881118040123 РИНЦ OpenAlex

Submitted:	Jan 10, 2018
Published print:	Jul 1, 2018
Published online:	Aug 4, 2018

Web of science:	WOS:000440802700017
Scopus:	2-s2.0-85051136433
Elibrary:	35721665
Chemical Abstracts:	2018:1445900
OpenAlex:	W2886468883

DB	Citing
Web of science	5
Scopus	4
Elibrary	3
OpenAlex	5