Valorization of Biomass Derived Terpene Compounds by Catalytic Amination | Sciact - CRIS-system of Boreskov Institute of Catalysis

Valorization of Biomass Derived Terpene Compounds by Catalytic Amination Review

Journal

Catalysts
ISSN: 2073-4344

Output data

Year: 2018, Volume: 8, Number: 9, Article number : 365, Pages count : 36 DOI: 10.3390/catal8090365

Tags

terpenes; terpenoids; biomass; heterogeneous and homogeneous catalysts; amination; transition metals; supported metals

Authors

Simakova Irina L. ^1,2 , Simakov Andrey V. ³ , Murzin Dmitry Yu. ⁴

Affiliations

1	Boreskov Institute of Catalysis, pr. Lavrentieva, 5, Novosibirsk 630090, Russia
2	Department of Natural Sciences, Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russia
3	Centro de Nanociencias y Nanotecnología, Universidad Nacional Autónoma de México, km. 107 Carretera Tijuana a Ensenada, Ensenada C.P. 22860, Baja California, Mexico
4	Johan Gadolin Process Chemistry Centre, Åbo Akademi University, FI-20500 Turku/Åbo, Finland

Funding (1)

Russian Foundation for Basic Research

18-53-45013

This review fills an apparent gap existing in the literature by providing an overview of the readily available terpenes and existing catalytic protocols for preparation of terpene-derived amines. To address the role of solid catalysts in amination of terpenes the same reactions with homogeneous counterparts are also discussed. Such catalysts can be considered as a benchmark, which solid catalysts should match. Although catalytic systems based on transition metal complexes have been developed for synthesis of amines to a larger extent, there is an apparent need to reduce the production costs. Subsequently, homogenous systems based on cheaper metals operating by nucleophilic substitution (e.g., Ni, Co, Cu, Fe) with a possibility of easy recycling, as well as metal nanoparticles (e.g., Pd, Au) supported on amphoteric oxides should be developed. These catalysts will allow synthesis of amine derivatives of terpenes which have a broad range of applications as specialty chemicals (e.g., pesticides, surfactants, etc.) and pharmaceuticals. The review will be useful in selection and design of appropriate solid materials with tailored properties as efficient catalysts for amination of terpenes.

Simakova I.L. , Simakov A.V. , Murzin D.Y.
Valorization of Biomass Derived Terpene Compounds by Catalytic Amination

Catalysts. 2018. V.8. N9. 365 :1-36. DOI: 10.3390/catal8090365 WOS Scopus РИНЦ ANCAN OpenAlex

Full text from publisher

Submitted:	Jul 30, 2018
Accepted:	Aug 26, 2018
Published online:	Aug 29, 2018
Published print:	Sep 1, 2018

Web of science:	WOS:000448331700025
Scopus:	2-s2.0-85052618689
Elibrary:	35754168
Chemical Abstracts:	2018:2050946
Chemical Abstracts (print):	170:382137
OpenAlex:	W2889486626

DB	Citing
Web of science	13
Scopus	16
Elibrary	12
OpenAlex	16