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Effect of Preparation Route on Sr2TiO4 Catalyst for the Oxidative Coupling of Methane Full article

Journal Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905
Output data Year: 2018, Volume: 117, Pages: 43-48 Pages count : 6 DOI: 10.1016/j.catcom.2018.08.001
Tags Strontium titanates, Layered perovskite structure, Oxidative coupling of methane
Authors Ivanova Y.A. 1 , Sutormina E.F. 1 , Rudina N.A. 1 , Nartova A.V. 1,2 , Isupova L.A. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS, pr. Lavrentieva, 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova St., 2, Novosibirsk 630090, Russia

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0004

Abstract: Four different preparation routes were used to synthesize Sr2TiO4 with the structure of layered perovskite: sol-precipitation (SP), co-precipitation (CO), citrate precursor (CT) and mechanochemical (MA) methods with further calcinations at 1100 °C. The XDR, XPS, BET, SEM techniques showed that the different preparation routes caused the formation of layered perovskite phase with different admixture phases, particle sizes and the surface enrichment with layered perovskite (for SP and MA samples) or strontium oxide (for CO and CT samples). The trend of increasing of CH4 conversion and C2-yield in oxidative coupling of methane at 800-900 °C was found to be the following: SP≈MA > CO > CT samples. The C2-yield of the most active catalysts was measured to be about 12%.
Cite: Ivanova Y.A. , Sutormina E.F. , Rudina N.A. , Nartova A.V. , Isupova L.A.
Effect of Preparation Route on Sr2TiO4 Catalyst for the Oxidative Coupling of Methane
Catalysis Communications. 2018. V.117. P.43-48. DOI: 10.1016/j.catcom.2018.08.001 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jun 5, 2018
Accepted: Aug 1, 2018
Published online: Aug 8, 2018
Published print: Dec 1, 2018
Identifiers:
Web of science: WOS:000447480600009
Scopus: 2-s2.0-85054063974
Elibrary: 35744220
Chemical Abstracts: 2018:1656378
Chemical Abstracts (print): 169:359678
OpenAlex: W2886010319
Citing:
DB Citing
Web of science 21
Scopus 25
Elibrary 21
OpenAlex 26
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