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Promoting Effect of 4-Dimethylaminopyridine on Selective Oxidation of Benzyl Alcohol over MoVTeNb Mixed Oxides Научная публикация

Журнал Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905
Вых. Данные Год: 2018, Том: 117, Страницы: 49-52 Страниц : 4 DOI: 10.1016/j.catcom.2018.08.025
Ключевые слова Multicomponent vanadium-based metal oxides; Selective oxidation; DMAP; Nucleophilic assistance
Авторы Koltunov Konstantin Yu. 1,2 , Ishchenko Evgeniya V. 1 , Sobolev Vladimir I. 1,3
Организации
1 Boreskov Institute of Catalysis, Russian Academy of Sciences, Pr. Akademika Lavrentieva, 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova, 2, Novosibirsk 630090, Russia
3 Tomsk State University, 36 Lenina Ave., Tomsk 634050, Russia

Информация о финансировании (1)

1 Федеральное агентство научных организаций России 0303-2016-0006 (V.44.1.6)

Реферат: A liquid phase oxidation of benzyl alcohol with 1 atm molecular oxygen catalyzed by MoVTeNb mixed oxides has been investigated. It is demonstrated that 4-dimethylaminopyridine (DMAP) acting as a co-catalyst, notably accelerates the reaction, as well as influences the ratio of the reaction products (benzaldehyde, benzyl benzoate and benzoic acid). The findings can be interpreted in terms of the involvement of DMAP (a good enough N-nucleophile) in the process of chemo-desorption of oxygenates formed on the catalyst surface.
Библиографическая ссылка: Koltunov K.Y. , Ishchenko E.V. , Sobolev V.I.
Promoting Effect of 4-Dimethylaminopyridine on Selective Oxidation of Benzyl Alcohol over MoVTeNb Mixed Oxides
Catalysis Communications. 2018. V.117. P.49-52. DOI: 10.1016/j.catcom.2018.08.025 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 11 июл. 2018 г.
Принята к публикации: 27 авг. 2018 г.
Опубликована online: 29 авг. 2018 г.
Опубликована в печати: 1 дек. 2018 г.
Идентификаторы БД:
Web of science: WOS:000447480600010
Scopus: 2-s2.0-85052620092
РИНЦ: 35739342
Chemical Abstracts: 2018:1656379
Chemical Abstracts (print): 169:370006
OpenAlex: W2888944550
Цитирование в БД:
БД Цитирований
Web of science 6
Scopus 6
РИНЦ 5
OpenAlex 6
Альметрики: