Promoting Effect of 4-Dimethylaminopyridine on Selective Oxidation of Benzyl Alcohol over MoVTeNb Mixed Oxides | Sciact - CRIS-система Института катализа

Promoting Effect of 4-Dimethylaminopyridine on Selective Oxidation of Benzyl Alcohol over MoVTeNb Mixed Oxides Научная публикация

Журнал

Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905

Вых. Данные

Год: 2018, Том: 117, Страницы: 49-52 Страниц : 4 DOI: 10.1016/j.catcom.2018.08.025

Ключевые слова

Multicomponent vanadium-based metal oxides; Selective oxidation; DMAP; Nucleophilic assistance

Авторы

Koltunov Konstantin Yu. ^1,2 , Ishchenko Evgeniya V. ¹ , Sobolev Vladimir I. ^1,3

Организации

1	Boreskov Institute of Catalysis, Russian Academy of Sciences, Pr. Akademika Lavrentieva, 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Pirogova, 2, Novosibirsk 630090, Russia
3	Tomsk State University, 36 Lenina Ave., Tomsk 634050, Russia

Информация о финансировании (1)

Федеральное агентство научных организаций России

0303-2016-0006 (V.44.1.6)

A liquid phase oxidation of benzyl alcohol with 1 atm molecular oxygen catalyzed by MoVTeNb mixed oxides has been investigated. It is demonstrated that 4-dimethylaminopyridine (DMAP) acting as a co-catalyst, notably accelerates the reaction, as well as influences the ratio of the reaction products (benzaldehyde, benzyl benzoate and benzoic acid). The findings can be interpreted in terms of the involvement of DMAP (a good enough N-nucleophile) in the process of chemo-desorption of oxygenates formed on the catalyst surface.

Koltunov K.Y. , Ishchenko E.V. , Sobolev V.I.
Promoting Effect of 4-Dimethylaminopyridine on Selective Oxidation of Benzyl Alcohol over MoVTeNb Mixed Oxides
Catalysis Communications. 2018. V.117. P.49-52. DOI: 10.1016/j.catcom.2018.08.025 WOS Scopus РИНЦ OpenAlex CAPlusCA

Поступила в редакцию:	11 июл. 2018 г.
Принята к публикации:	27 авг. 2018 г.
Опубликована online:	29 авг. 2018 г.
Опубликована в печати:	1 дек. 2018 г.

≡ Web of science:	WOS:000447480600010
≡ Scopus:	2-s2.0-85052620092
≡ РИНЦ:	35739342
≡ OpenAlex:	W2888944550
≡ Chemical Abstracts:	2018:1656379
≡ Chemical Abstracts (print):	169:370006

≡ Web of science	6	Сбор данных от 20.02.2026
≡ Scopus	6	Сбор данных от 15.02.2026
≡ РИНЦ	5	Сбор данных от 15.02.2026
≡ OpenAlex	6	Сбор данных от 15.02.2026