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Direct Conversion of Methanol Into Dimethoxymethane and Methyl Formate by Controlled Oxidation. Mechanistic Aspects Review

Journal Advanced Chemistry Letters
ISSN: 2326-747X , E-ISSN: 2326-7488
Output data Year: 2013, Volume: 1, Number: 3, Pages: 280-285 Pages count : 6 DOI: 10.1166/acl.2013.1038
Tags C1-BASED CHEMISTRY; DIMETHOXYMETHANE; METHANOL SELECTIVE OXIDATION; METHYL FORMATE; OXIDATIVE ESTERIFICATION
Authors Koltunov K.Yu. 1 , Sobolev V.I. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5, Lavrentev prospect, Novosibirsk, 630090

Abstract: Catalytic oxidation of methanol with molecular oxygen can lead to a convenient, one-stage formation of dimethoxymethane and methyl formate, which are regarded as valuable products of C1-based chemistry. Production of these derivatives instead of more expected parent compounds, such as formaldehyde and formic acid, is usually explained by combination of methanol oxidation and acid-catalyzed acetalization (esterification) of the in situ produced formaldehyde (formic acid). However, the mechanistic aspects of these important transformations remain unclear thus far. The paper includes brief overview on methanol selective oxidation to dimethoxymethane and methyl formate and focuses on possible reaction pathways for their formation. The proposed mechanism of the reaction involves intermediacy of semi-organic acetals and esters, readily reactive with water and methanol. This gives a plausible explanation for predominant selectivity toward formaldehyde, formic acid, dimethoxymethane and methyl formate depending on reaction conditions.
Cite: Koltunov K.Y. , Sobolev V.I.
Direct Conversion of Methanol Into Dimethoxymethane and Methyl Formate by Controlled Oxidation. Mechanistic Aspects
Advanced Chemistry Letters. 2013. V.1. N3. P.280-285. DOI: 10.1166/acl.2013.1038 РИНЦ ANCAN OpenAlex
Dates:
Published print: Sep 1, 2013
Identifiers:
Elibrary: 21972988
Chemical Abstracts: 2014:883618
Chemical Abstracts (print): 161:755504
OpenAlex: W2334940001
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