The Comparison of Sulfide CoMo/γ-Al2O3 and NiMo/γ-Al2O3 Catalysts in Methyl Palmitate and Methyl Heptanoate Hydrodeoxygenation Conference Abstracts
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2nd European Conference of Chemical Engineering (ECCE'11) 10-12 Dec 2011 , Puerto De La Cruz, Tenerife |
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| Source | ECC'11/ECME'11: Proceedings of the 2nd European conference of Control, and Proceedings of the 2nd European conference on Mechanical Engineering, December 2011 Compilation, World Scientific and Engineering Academy and Society (WSEAS). Stevens Point, Wisconsin, United States.2011. |
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| Output data | Year: 2011, Pages: 24-29 Pages count : 6 | ||||
| Tags | biofuels; hydrodeoxygenation; methyl palmitate; methyl heptanoate; CoMoS/γ-Al2O3; NiMoS/γ-Al2O3 | ||||
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Abstract:
The hydrodeoxygenation of methyl palmitate and methyl heptanoate as the model compounds of bio-oil in the presence of sulfided CoMo/γ-Al2O3 and NiMo/γ-Al2O3 catalysts was studied at the temperature 300oC and hydrogen pressure 35 bars. In hydrodeoxygenation experiments the performances of sulfided CoMo and NiMo catalysts were compared in terms of methyl palmitate and methyl heptanoate conversions, oxygen removal, and the reaction products distribution. The CoMo/γ-Al2O3 catalyst exhibited higher catalytic activity in the methyl palmitate HDO than the NiMo/γ-Al2O3 using n-tetradecane as a solvent. The main product obtained over CoMo/γ-Al2O3 catalyst was hexadecane whereas pentadecane is preferably formed over NiMo/γAl2O3 catalyst, pointing to different reaction route of HDO. The tentative reaction scheme of methyl palmitate transformation was considered in comparison with ones obtained for methyl heptanoate hydrodeoxygenation.
Cite:
Deliy I.V.
, Vlasova E.N.
, Nuzhdin A.L.
, Bukhtiyarova G.A.
The Comparison of Sulfide CoMo/γ-Al2O3 and NiMo/γ-Al2O3 Catalysts in Methyl Palmitate and Methyl Heptanoate Hydrodeoxygenation
In compilation ECC'11/ECME'11: Proceedings of the 2nd European conference of Control, and Proceedings of the 2nd European conference on Mechanical Engineering, December 2011. – World Scientific and Engineering Academy and Society (WSEAS)., 2011. – C.24-29. ANCAN OpenAlex
The Comparison of Sulfide CoMo/γ-Al2O3 and NiMo/γ-Al2O3 Catalysts in Methyl Palmitate and Methyl Heptanoate Hydrodeoxygenation
In compilation ECC'11/ECME'11: Proceedings of the 2nd European conference of Control, and Proceedings of the 2nd European conference on Mechanical Engineering, December 2011. – World Scientific and Engineering Academy and Society (WSEAS)., 2011. – C.24-29. ANCAN OpenAlex
Identifiers:
| Chemical Abstracts: | 2012:515962 |
| Chemical Abstracts (print): | 157:469598 |
| OpenAlex: | W100878150 |
Citing:
| DB | Citing |
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| OpenAlex | 1 |