Experimental and Simulation Evidence of a Corkscrew Motion for Benzene in the Metal−Organic Framework MIL-47 | Sciact - CRIS-система Института катализа

Experimental and Simulation Evidence of a Corkscrew Motion for Benzene in the Metal−Organic Framework MIL-47 Научная публикация

Журнал

The Journal of Physical Chemistry C
ISSN: 1932-7447 , E-ISSN: 1932-7455

Вых. Данные

Год: 2012, Том: 116, Номер: 28, Страницы: 15093-15098 Страниц : 6 DOI: 10.1021/jp302995b

Ключевые слова

MOLECULAR-DYNAMICS SIMULATION; ELASTIC NEUTRON-SCATTERING; NUCLEAR-MAGNETIC-RESONANCE; SELECTIVE ADSORPTION; XYLENE ISOMERS; FORCE-FIELD; H-2 NMR; DIFFUSION; SEPARATION; ZEOLITES

Авторы

Kolokolov Daniil I. ^1,2 , Jobic Herve ¹ , Stepanov Alexander G. ² , Ollivier Jacques ³ , Rives Sebastien ^1,4 , Maurin Guillaume ⁴ , Devic Thomas ⁵ , Serre Christian ⁵ , Férey Gerard ⁵

Организации

1	Institut de Recherches sur la Catalyse et l′Environnement de Lyon, UMR CNRS 5256, UniversitéLyon 1, 2. Av. A. Einstein, 69626 Villeurbanne, France
2	Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia
3	Institut Laue Langevin, BP 156, 38042 Grenoble, France
4	Institut Charles Gerhardt Montpellier, UMR CNRS 5253, ENSCM, Place E. Bataillon, 34095 Montpellier, France
5	Institut Lavoisier, UMR CNRS 8180, Universitéde Versailles Saint-Quentin-en-Yvelines, 78035 Versailles, France

Информация о финансировании (3)

1	Российский фонд фундаментальных исследований	12-03-00316
2	Российский фонд фундаментальных исследований	09-03-93113
3	European Commission	228862 FP7-NMP-2008-LARGE-2 MACADEMIA

Some bacteria move with a corkscrew motion, meeting less resistance from surrounding water. A spiral movement is also considered during RNA polymerase translocation and it has been observed for water and proteins. We have found that benzene molecules confined in the metal−organic framework MIL-47 move in a corkscrew fashion. This spectacular diffusion effect could be put into evidence by combining experimental and computation tools; the two experimental techniques, quasielastic neutron scattering and 2H NMR, cover a wide range of time scales.

Kolokolov D.I. , Jobic H. , Stepanov A.G. , Ollivier J. , Rives S. , Maurin G. , Devic T. , Serre C. , Férey G.
Experimental and Simulation Evidence of a Corkscrew Motion for Benzene in the Metal−Organic Framework MIL-47
The Journal of Physical Chemistry C. 2012. V.116. N28. P.15093-15098. DOI: 10.1021/jp302995b WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	29 мар. 2012 г.
Принята к публикации:	28 июн. 2012 г.
Опубликована online:	10 июл. 2012 г.
Опубликована в печати:	19 июл. 2012 г.

Web of science:	WOS:000306503200043
Scopus:	2-s2.0-84863891949
РИНЦ:	20477303
Chemical Abstracts:	2012:945742
Chemical Abstracts (print):	157:273981
OpenAlex:	W2332038349

БД	Цитирований
Web of science	36
Scopus	38
РИНЦ	34
OpenAlex	44