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On the Mechanisms of Selective Bioinspired Oxidations Catalyzed by Aminopyridine Manganese Complexes Тезисы доклада

Конференция EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 авг. - 4 сент. 2015 , Казань
Сборник EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Сборник, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ
Вых. Данные Год: 2015, Номер статьи : ISO-OP13, Страниц : 2
Авторы Talsi E.P. 1,2 , Ottenbacher R.V. 1,2 , Bryliakov K.P. 1,2
Организации
1 Novosibirsk State University, Novosibirsk, Russia
2 Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 14-03-00102

Реферат: Insights into the mechanisms of (1) selective epoxidations and (2) C-H oxidations mediated by aminopyridine manganese complexes have been achieved on the basis of kinetic (Hammett plot analysis, KIE measuments) and isotopic (18O) labelling studies. For the first time, the incorporation of labelled oxygen into the products of oxidation catalyzed by aminopyridine manganese complexes in the presence of H2 18O was observed. The data obtained bear evidence in favour of the key role of MnV-oxo species, the most likely catalytically active sites of both processes.
Библиографическая ссылка: Talsi E.P. , Ottenbacher R.V. , Bryliakov K.P.
On the Mechanisms of Selective Bioinspired Oxidations Catalyzed by Aminopyridine Manganese Complexes
В сборнике EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.2078-2079. – ISBN 978-5-906376-10-7.
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