Capillary Microreactor with PdZn/(Ti,Ce)O2 Coating for Selective Hydrogenation of 2-Methyl-3-Butyne-2-ol | Sciact - CRIS-system of Boreskov Institute of Catalysis

Capillary Microreactor with PdZn/(Ti,Ce)O2 Coating for Selective Hydrogenation of 2-Methyl-3-Butyne-2-ol Conference Abstracts

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Source

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Output data

Year: 2015, Article number : IV-PP101, Pages count : 2

Authors

Okhlopkova L.B. ¹ , Kerzhentsev M.A. ¹ , Ismagilov Z.R. ^1,2

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Institute of Coal Chemistry and Material Science, Kemerovo, Russia

The performance of a capillary microreactor coated with mesoporous Pd/(Ti,Ce)O2 and Pd80 Zn20/(Ti, Ce)O2 thin films has been tested in the selective hydrogenation of alkyne alcohol. Catalytic coatings were prepared by dip-coating method of the inner wall of a fused silica capillary with an internal diameter of 250 µm using nanoparticles-based precursor solution. The capillary microreactors were tested in the hydrogenation of 2-methyl-3-butyne-2-ol (0.05-0.3M solution with methanol as a solvent) in 313-323 К temperature range and at the hydrogen partial pressure ranging from 0.3 to 1.0. The highest selectivity of 94% to 2-methyl-3-butene-2-ol was obtained at 99.8% conversion on the Pd80Zn20/(Ti,Ce)O2 coating

Okhlopkova L.B. , Kerzhentsev M.A. , Ismagilov Z.R.
Capillary Microreactor with PdZn/(Ti,Ce)O2 Coating for Selective Hydrogenation of 2-Methyl-3-Butyne-2-ol
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.1548-1549. – ISBN 978-5-906376-10-7.

No identifiers

Пока нет цитирований