Development of Bifunctional Catalysts Containing Ru and CsHPA for One-Pot Conversion of Polysaccharides to Polyols | Sciact - CRIS-system of Boreskov Institute of Catalysis

Development of Bifunctional Catalysts Containing Ru and CsHPA for One-Pot Conversion of Polysaccharides to Polyols Conference Abstracts

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Source

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Output data

Year: 2015, Pages: 1446-1447 Pages count : 2

Authors

Gromov N.V. ¹ , Taran O.P. ^1,2 , Timofeeva M.N. ^1,2 , Zhizhina E.G. ¹ , Rodikova Yu.A. ¹ , Parmon V.N. ^1,3

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State Technical University, Novosibirsk, Russia
3	Novosibirsk State University, Novosibirsk, Russia

Funding (1)

Russian Foundation for Basic Research

14-03-00854

Cs salts of HPAs with different HPA structures and Cs content as well as Ru catalysts supported on carbon and CsHPAs were prepared. All the catalysts were characterized by the different analytical methods and tested for the stability in the hydrothermal conditions. The synthesized bifunctional Ru/CsHPA catalysts (where HPA was Сs2HPW12O40 and Cs3HSiW12O40) showed very high stability, activity and selectivity in the one-pot hydrolitic hydrogenation of polysaccharides (cellulose and xylan). High yields of sorbitol or xylitol up to 60 and 70% respectively were archived.

Gromov N.V. , Taran O.P. , Timofeeva M.N. , Zhizhina E.G. , Rodikova Y.A. , Parmon V.N.
Development of Bifunctional Catalysts Containing Ru and CsHPA for One-Pot Conversion of Polysaccharides to Polyols
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.1446-1447. – ISBN 978-5-906376-10-7.

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