Ethanol Selective Oxidation into Syngas over Pt-Promoted Fluorite-Like Oxide: SSITKA and Pulse Microcalorimetry Study | Sciact - CRIS-system of Boreskov Institute of Catalysis

Ethanol Selective Oxidation into Syngas over Pt-Promoted Fluorite-Like Oxide: SSITKA and Pulse Microcalorimetry Study Conference Abstracts

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Source

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Output data

Year: 2015, Pages: 2060-2061 Pages count : 2

Authors

Simonov M.N. ^1,2 , Sadykov V.A. ^1,2 , Rogov V.A. ^1,2 , Bobin A.S. ^1,2 , Sadovskaya E.M. ^1,2 , Mezentseva N.V. ^1,2 , Roger A.-C. ³ , van Veen A.C. ⁴

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	University of Strasbourg, Strasbourg, France
4	University of Warwick, Warwick, UK

Funding (3)

1	Russian Foundation for Basic Research	12-03-93115
2	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO
3	The Ministry of Education and Science of the Russian Federation

Catalysts based on oxides with a high lattice oxygen mobility and reactivity are known to be able to efficiently transform ethanol into syngas by selective oxidation. Mechanism of this reaction over Pt/ Pr0.15Sm0.15Ce0.35Zr0.35O2 catalyst was studied by using SSITKA and pulse microcalorimetry. The rate–determining step is C-C bond rupture in ethanol/acetaldehyde molecules, while C-H bond breaking in the ethanol dehydrogenation step proceeds easily. The mechanism is described by step-wise red–ox scheme including ethanol oxidative decomposition on Pt sites with participation of bridging oxygen species (with the heat of adsorption ~ 550 kJ/mol O2) located at Pt-oxide interface followed by fast reoxidation of reduced support sites by O2. Rapid oxygen migration from oxide sites to Pt provides conjugation between these steps, thus suppressing coking

Simonov M.N. , Sadykov V.A. , Rogov V.A. , Bobin A.S. , Sadovskaya E.M. , Mezentseva N.V. , Roger A.-C. , van Veen A.C.
Ethanol Selective Oxidation into Syngas over Pt-Promoted Fluorite-Like Oxide: SSITKA and Pulse Microcalorimetry Study
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.2060-2061. – ISBN 978-5-906376-10-7.

No identifiers

Пока нет цитирований