Hierarchically Porous Fe-Silicalites for Total Oxidation of Organic Molecules | Sciact - CRIS-system of Boreskov Institute of Catalysis

Hierarchically Porous Fe-Silicalites for Total Oxidation of Organic Molecules Conference Abstracts

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Source

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Output data

Year: 2015, Pages: 1661-1662 Pages count : 2

Authors

Sashkina K.A. ^1,2,3 , Labko V.S. ⁴ , Parkhomchuk E.V. ^1,2,3

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Research and Education Centre, NSU, Novosibirsk, Russia
4	State Scientific Institution “The Joint Institute for Power and Nuclear Research – Sosny”, Minsk, Belarus

Funding (2)

1	Russian Science Foundation	14-13-01155
2	Skolkovo Foundation	1 от 28.11.2013

Series of hierarchical Fe-silicalites were prepared by two approaches: template synthesis and patterning Fe-silicalite nanocrystals. The synthesized samples were characterized by a number of methods: laser diffraction analysis, X-ray diffraction, scanning and transmission electron microscopy, energy-dispersive X-ray spectroscopy, argon and nitrogen adsorption measurements, inductively coupled plasma optical emission spectrometry, UV visible diffuse reflectance spectroscopy and temperature-programmed desorption of ammonia. Hierarchically porous Fe-silicalites were tested in total liquid phase catalytic oxidation of different organic molecules, including phenol, the natural polymer – lignin, macrolide antibiotic – clarithromycin lactobionate and metal ion complexing agent – EDTA by H2O2 at low temperatures (298-323 K) compared with Fe-silicalite microspheres and homogeneous Fenton reagent. Performances of hierarchical Fe-silicalites in oxidation of large organic molecules by hydrogen peroxide were significantly improved vs. the reference Fe-silicalite microbeads, resulted from increasing catalytic sites accessibility.

Sashkina K.A. , Labko V.S. , Parkhomchuk E.V.
Hierarchically Porous Fe-Silicalites for Total Oxidation of Organic Molecules
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.1661-1662. – ISBN 978-5-906376-10-7.

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