Preparation of Metal–Polymer Composites through the Thermolysis of Fe(II), Co(II), and Ni(II) Maleates | Sciact - CRIS-system of Boreskov Institute of Catalysis

Preparation of Metal–Polymer Composites through the Thermolysis of Fe(II), Co(II), and Ni(II) Maleates Full article

Journal

Inorganic Materials
ISSN: 0020-1685 , E-ISSN: 1608-3172

Output data

Year: 2013, Volume: 49, Number: 10, Pages: 1055-1060 Pages count : 6 DOI: 10.1134/S0020168513100142

Tags

Polymer Matrix; Thermolysis; Graphene Layer; Polymer Shell; Graphene Shell

Authors

Yudanova L.I. ¹ , Logvinenko V.A. ¹ , Yudanov N.F. ¹ , Rudina N.A. ² , Ishchenko A.V. ² , Semyannikov P.P. ¹ , Sheludyakova L.A. ¹ , Alferova N.I. ¹ , Romanenko A.I. ¹ , Anikeeva O.B. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

Metal-polymer composites have been prepared through the thermolysis of the [M1(H2O)2(C4H2O4)] · H2O (M1 = Co(II), Ni(II)) neutral maleates and [M2(H2O)4(C4H3O4)2] (M2 = Fe(II), Co(II), Ni(II)) acid maleates. In the polymer matrix of the Fe-containing composite, we identified metal, Fe2O3, and Fe3O4 particles, with slight densification of the matrix around them. The polymer matrix of the cobalt maleate-derived composite contained four types of nanoparticles: α-Co, β-Co, and CoO in polymer shells and Co3O4 with no polymer shell. The decomposition of the nickel maleates yielded homogeneous nickel nanoparticles (4–5 nm) covered with two to five graphene layers. The Co-containing composite was found to be a dielectric. The Ni-containing composite exhibited variable range hopping conduction in the range T ≤ 50 K.

Yudanova L.I. , Logvinenko V.A. , Yudanov N.F. , Rudina N.A. , Ishchenko A.V. , Semyannikov P.P. , Sheludyakova L.A. , Alferova N.I. , Romanenko A.I. , Anikeeva O.B.
Preparation of Metal–Polymer Composites through the Thermolysis of Fe(II), Co(II), and Ni(II) Maleates
Inorganic Materials. 2013. V.49. N10. P.1055-1060. DOI: 10.1134/S0020168513100142 WOS Scopus РИНЦ ANCAN OpenAlex

Юданова Л.И. , Логвиненко В.А. , Юданов Н.Ф. , Рудина Н.А. , Ищенко А.В. , Семянников П.П. , Шелудякова Л.А. , Алферова Н.И. , Романенко А.И. , Аникеева О.Б.
Синтез композитов металл/полимер термолизом солей малеиновой кислоты Fe(II), Co(II) и Ni(II)
Неорганические материалы. 2013. Т.49. №10. С.1138-1143. DOI: 10.7868/S0002337X1310014X РИНЦ OpenAlex

Submitted:	Feb 15, 2013
Published online:	Aug 28, 2013
Published print:	Oct 1, 2013

Web of science:	WOS:000323659500017
Scopus:	2-s2.0-84883738298
Elibrary:	20450673
Chemical Abstracts:	2013:1550196
Chemical Abstracts (print):	160:311522
OpenAlex:	W1981716612

DB	Citing
Web of science	19
Scopus	23
Elibrary	21
OpenAlex	24