Ethanol Conversion into Chemicals over Au-M Containing Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Ethanol Conversion into Chemicals over Au-M Containing Catalysts Conference Abstracts

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Source

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Output data

Year: 2015, Pages: 89-90 Pages count : 2

Authors

Chistyakov A.V. ^1,2 , Nikolaev S.A. ³ , Zharova P.A. ¹ , Kriventsov V.V. ⁴ , Tsodikov M.V. ^1,2

Affiliations

1	Topchuev Institute of Petrochemical Synthesis RAS, Moscow, Russia
2	Gubkin Russian State University of Oil and Gas, Moscow, Russia
3	Lomonosov Moscow State University, Moscow, Russia
4	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

Funding (3)

1	Russian Foundation for Basic Research	13-03-12034 (01201367680)
2	Russian Foundation for Basic Research	15-03-06479
3	Council for Grants of the President of the Russian Federation	МК-5328.2014.3

Direct catalytic valorization of ethanol either to olefins fractions C3-C8 or 1-butanol, 1-hexanol and 1-octanol over Au-Cu and Au-Ni containing catalysts was studied. Selectivity of 1-butanol formation was 75 %. First time ever over heterogeneous catalysts the reaction of ethanol and iso-propanol was carried on resulted in 3-methyl-2-butanol formation that is precursor of valuable monomer – isoprene. The peculiarities of the reaction mechanism are discussed, with the specific surface and electronic features of the prepared catalysts being considered. Found that growing the Au particles by forming the mixed MO/Au (M- Cu, Ni) particles resulted in an increased aim products selectivity

Chistyakov A.V. , Nikolaev S.A. , Zharova P.A. , Kriventsov V.V. , Tsodikov M.V.
Ethanol Conversion into Chemicals over Au-M Containing Catalysts
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.89-90. – ISBN 978-5-906376-10-7.

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