Methylation Reaction of Aromatic NH-Heterocycles with Using Supercritical Methanol: Competitive Homogeneous and Heterogeneous Catalysis by Si-Containing Compounds Тезисы доклада
Конференция |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 авг. - 4 сент. 2015 , Казань |
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Сборник | EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts Сборник, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ |
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Вых. Данные | Год: 2015, Страницы: 1313-1314 Страниц : 2 | ||||
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Информация о финансировании (1)
1 | Российский фонд фундаментальных исследований | 13-03-00595 |
Реферат:
Experimental data obtained point to the mixed and competitive heterogeneous–homogeneous catalytic effect of Si-containing compounds on the methylation reaction of some aromatic NH-heterocycles with methanol at 350°C without additional methylating reagents. The starting SiO2-containing material (quartz, Pyrex glass or silica gel) reacts with methanol at supercritical conditions to form in-situ tetramethyl orthosilicate (TMOS). Both solid SiO2 and liquid TMOS have demonstrated the pronounced and comparable catalytic effect
Библиографическая ссылка:
Martyanov O.N.
, Chibiryaev A.M.
, Kozhevnikov I.V.
Methylation Reaction of Aromatic NH-Heterocycles with Using Supercritical Methanol: Competitive Homogeneous and Heterogeneous Catalysis by Si-Containing Compounds
В сборнике EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.1313-1314. – ISBN 978-5-906376-10-7.
Methylation Reaction of Aromatic NH-Heterocycles with Using Supercritical Methanol: Competitive Homogeneous and Heterogeneous Catalysis by Si-Containing Compounds
В сборнике EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.1313-1314. – ISBN 978-5-906376-10-7.
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