Hydrogen Production via Ethanol Steam Reforming over Supported Nikelates: From Powders to Structured Catalysts | Sciact - CRIS-система Института катализа

Hydrogen Production via Ethanol Steam Reforming over Supported Nikelates: From Powders to Structured Catalysts Тезисы доклада

Конференция

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 авг. - 4 сент. 2015 , Казань

Сборник

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Сборник, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Вых. Данные

Год: 2015, Страницы: 1210-1211 Страниц : 2

Авторы

Arapova M. ¹ , Pavlova S. ¹ , Larina T. ¹ , Rogov V. ¹ , Krieger T. ¹ , Sadykov V. ^1,2 , Glazneva T. ¹ , Smorygo O. ³ , Parkhomenko K. ⁴ , Roger A.-C. ⁴

Организации

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Institute of Powder Metallurgy, Minsk, Belarus
4	Unversity of Strasbourg, Strasbourg, France

Информация о финансировании (3)

1	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO
2	Российский фонд фундаментальных исследований	12-03-93115
3	Министерство образования и науки Российской Федерации

The catalysts mLnNi0.9Ru0.1О3/nMg-γ-Al2O3 (Ln = La, Pr, m=10-20%wt, n=6-15%wt) have been prepared by impregnation, characterized by XRD, BET, TEM with EDX, UV-vis, XPS, TPR-H2, FTIRS of CO test molecule and studied in ethanol steam reforming as fractions and layers on structured ceramic and Ni-Al alloy substrates. The influence of Ln nature and Mg concentration on the structural and redox properties of the catalysts have been elucidated. High activity and coking stability of catalysts are provided by a high dispersion of metallic Ni and Ni-Ru alloy due to strong interaction with LnOx/MgO/γ-Al2O3 support and suppressing support acidity by Mg/Ln cations. The optimal catalyst supported on Ni-Al foam substrate shows high and stable performance in a realistic reaction mixture during 50 hours.

Arapova M. , Pavlova S. , Larina T. , Rogov V. , Krieger T. , Sadykov V. , Glazneva T. , Smorygo O. , Parkhomenko K. , Roger A.-C.
Hydrogen Production via Ethanol Steam Reforming over Supported Nikelates: From Powders to Structured Catalysts
В сборнике EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.1210-1211. – ISBN 978-5-906376-10-7.

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