Oxidation of n-Heptane over Sphere Catalysts with a Composition of TiO2-SiO2-MxOy, where M is Со or Ni | Sciact - CRIS-system of Boreskov Institute of Catalysis

Oxidation of n-Heptane over Sphere Catalysts with a Composition of TiO2-SiO2-MxOy, where M is Со or Ni Conference Abstracts

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Source

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Output data

Year: 2015, Pages: 575-576 Pages count : 2

Authors

Shamsutdinova A. ¹ , Zharkova V. ¹ , Brichkov A. ¹ , Glazneva T. ² , Bobkova L. ¹ , Larina T. ² , Paukshtis E. ^1,2 , Parmon V. ^1,2 , Kozik V. ¹

Affiliations

1	National Research Tomsk State University, Tomsk, Russia
2	Boreskov institute of catalysis SB RAN, Novosibirsk, Russia

Funding (1)

The Ministry of Education and Science of the Russian Federation

11.801.2014/K

The preparation technique of new composite catalytic materials in the form of hollow spheres was developed. TiO2-SiO2 composites were modified by nickel and cobalt. After annealing, the spatial structure of sphere samples was studied by X-ray microtomography on a digital 3D microtomograph. The state of the cations of transition elements and titanium was characterized by UV-Vis DR spectroscopy. The catalysts were tested in the oxidation of n-heptane. It was found that besides the destructive oxidation, the oxidative dehydrogenation of n-heptane and formation of partial oxidation products such as ketones and esters took place. The selectivity towards the partial oxidation products at 400-450oC reaches 63% on Ni modified catalyst

Shamsutdinova A. , Zharkova V. , Brichkov A. , Glazneva T. , Bobkova L. , Larina T. , Paukshtis E. , Parmon V. , Kozik V.
Oxidation of n-Heptane over Sphere Catalysts with a Composition of TiO2-SiO2-MxOy, where M is Со or Ni
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.575-576. – ISBN 978-5-906376-10-7.

No identifiers

Пока нет цитирований