Pt-Sn Catalysts for Biomass Conversion into Fuel Components and Chemicals | Sciact - CRIS-system of Boreskov Institute of Catalysis

Pt-Sn Catalysts for Biomass Conversion into Fuel Components and Chemicals Conference Abstracts

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Source

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Output data

Year: 2015, Article number : I-PP80, Pages count : 2

Authors

Zharova P.A. ¹ , Chistyakov A.V. ^1,2 , Kriventsov V.V. ³ , Shapovalov S.S. ⁴ , Murzin V.Y. ⁵ , Tsodikov M.V. ^1,2

Affiliations

1	Topchuev Institute of Petrochemical Synthesis RAS, Moscow, Russia
2	Gubkin Russian State University of Oil and Gas, Moscow, Russia
3	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
4	Kurnakov Institute of General and Inorganic Chemistry RAS, Moscow, Russia
5	National research centre "Kurchatov institute", Moscow, Russia

Funding (3)

1	Russian Foundation for Basic Research	13-03-12034 (01201367680)
2	Russian Foundation for Basic Research	15-03-06479
3	Council for Grants of the President of the Russian Federation	МК-5328.2014.3

In TIPS RAS was found that ethanol and rapeseed oil could be converted into a number of fuel hydrocarbons over industrial Pt/Al2O3 catalyst. Aim of the current work is ethanol and rapeseed oil high selective conversion into fuel components and monomers over Pt-Sn/Al2O3 catalysts with different molar ratio of active components. The most prospect catalyst for ethanol and rapeseed oil conversion was found to be 1Pt-5Sn/Al2O3. Over that carbon mass of initial oil could be converted into alkanes and olefins with only two C18 and C3-C4 fractions. So selective process may be only when oxygen of initial oil converts in water. Optimal conditions for ethanol conversion were found, that provides yield of alkanes and olefins C3-C8 up to 50 wt.%. Obtained results allow minimizing loss of initial carbon weight due to cancelation of carboxyl fragment of fatty acids and glycerol conversion into methane and carbon oxides.

Zharova P.A. , Chistyakov A.V. , Kriventsov V.V. , Shapovalov S.S. , Murzin V.Y. , Tsodikov M.V.
Pt-Sn Catalysts for Biomass Conversion into Fuel Components and Chemicals
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.256-257. – ISBN 978-5-906376-10-7.

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