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Development of Acid Carbon Materials: Preparation and Use as Acid Catalysts Тезисы доклада

Конференция Catalyst Design: 4th International School-Conference on Catalysis for Young Scientists
05-06 сент. 2015 , Казань
Сборник CATALYST DESIGN. From Molecular to Industrial level / 4th International School-Conference on Catalysis for Young Scientists (ISCC-2015) (September 5-6, 2015 Kazan, Russia)
Сборник, BIC. Novosibirsk.2015. 218 c. ISBN 9785906376114. РИНЦ
Вых. Данные Год: 2015, Номер статьи : OP-1, Страниц : 1
Авторы Koskin A.P. 1 , Larichev Yu.V. 1,2
Организации
1 Boreskov Institute of Catalysis, SB RAS, Prospekt Akademika Lavrentieva 5, Novosibirsk, 630090, Russia
2 Novosibirsk State University, Pirogova Street 2, Novosibirsk, 630090, Russia

Информация о финансировании (3)

1 Российский фонд фундаментальных исследований 14-03-31851
2 Российский фонд фундаментальных исследований 14-03-31833
3 Министерство образования и науки Российской Федерации

Реферат: In this study we have developed synthetic methods for preparation acid carbon materials from available precursors such as heavy oil fraction, sulfuric acid and different templates (for example rice husk). The main advantage of our way of preparation is cheap precursors and easy variation of acid content in material and value of specific surface. Obtained composites were characterized by BET, SAXS, TEM and they are also tested in catalytic activity (esterification fatty acids reaction). The catalytic properties and durability of the obtained materials studied in the esterification reaction. Esterification of higher fatty acid was carried out at 80 °C in an ethanol–oleic acid (C17H33COOH) mixture (ethanol, 0.10 mol; oleic acid, 0.010 mol) under Ar atmosphere. Total density of the composite acid sites can be estimated via sulfur element analysis, because each sulfonic acid group constitutes a potential acid site. Elemental analysis data are well consistent with results on irreversible titration by pyridine solution
Библиографическая ссылка: Koskin A.P. , Larichev Y.V.
Development of Acid Carbon Materials: Preparation and Use as Acid Catalysts
В сборнике CATALYST DESIGN. From Molecular to Industrial level / 4th International School-Conference on Catalysis for Young Scientists (ISCC-2015) (September 5-6, 2015 Kazan, Russia). – BIC., 2015. – C.19. – ISBN 9785906376114.
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