Steam Reforming of Ethanol and Glycerol over Functionally Graded Nickelate-Based Catalysts: From Grain to Structured Catalysts | Sciact - CRIS-система Института катализа

Steam Reforming of Ethanol and Glycerol over Functionally Graded Nickelate-Based Catalysts: From Grain to Structured Catalysts Тезисы доклада

Конференция

French Conference on Catalysis (FCCat 1)
23-27 мая 2016 , Frejus

Сборник

Book of Abstracts - FCCAT1 - 2016
Сборник, 2016. 211 c.

Вых. Данные

Год: 2016, Номер статьи : PBBP-3, Страниц : 1

Авторы

Arapova Marina ^1,2 , Pavlova Svetlana ¹ , Parkhomenko Ksenia ² , Glazneva Tatiana ¹ , Larina Tatiana ¹ , Sadykov Vladislav ^1,2 , Roger Anne-Cécile ³ , Smorygo Oleg ⁴

Организации

1	Laboratory of deep oxidation catalysts, Boreskov Institute of Catalysis SB RAS, Lavrentieva 5, 630090 Novosibirsk, Russia
2	Novosibirsk State University, Pirogova 2, 630090 Novosibirsk, Russia
3	ICPEES, Université de Strasbourg, 25 rue Becquerel, 67087 Strasbourg cedex, France
4	Institute of Powder Metallurgy, 220005, Minsk, Belarus

In the present work, the catalysts mLnNi0.9Ru0.1О3/nMg-γ-Al2O3 (Ln = La, Pr, m=10-20%wt, n=6-15%wt) were synthesized and tested in ESR, steam and oxy-steam reforming of glycerol (GSR and GOSR) as granulated and structured ones. The influence of Mg content, Ln nature and preparation method on Ni(Ru) state and dispersion, catalysts stability to coking have been studied. Study of the catalysts activity in ESR and GSR shows that the presence of Mg provides considerably higher values of ethanol and glycerol conversion, hydrogen yield and coking stability as well. The optimal catalyst supported on structured foam substrate shows a high and stable performance in ESR in a pilot reactor in a realistic reaction mixture over 50 hours.

Arapova M. , Pavlova S. , Parkhomenko K. , Glazneva T. , Larina T. , Sadykov V. , Roger A-C. , Smorygo O.
Steam Reforming of Ethanol and Glycerol over Functionally Graded Nickelate-Based Catalysts: From Grain to Structured Catalysts
В сборнике Book of Abstracts - FCCAT1 - 2016. 2016. – C.137.

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