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Development of Monolithic Catalysts with Low Noble Metal Content for Diesel Vehicle Emission Control Full article

Conference 6th International Congress on Catalysis and Automotive Pollution Control
22-24 Oct 2003 , Brussels
Journal Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028
Output data Year: 2004, Volume: 30-31, Number: 1-4, Pages: 293-298 Pages count : 6 DOI: 10.1023/B:TOCA.0000029765.54179.c9
Tags Automotive exhaust purification, Catalytic combustion, Diesel emission control, Manganese-alumina catalyst, Multicomponent catalyst, Washcoated catalyst
Authors Yashnik S.A. 1 , Kuznetsov V.V. 1 , Ismagilov Z.R. 1 , Ushakov V.V. 1 , Danchenko N.M. 2 , Denisov S.P. 2
Affiliations
1 Boreskov Institute of Catalysis, Prosp. Akad. Lavrentieva, 5, Novosibirsk 630090, Russia
2 Ural Electrochemical Plant, Dzerzhinskogo st., 2, Novouralsk 624130, Russia

Funding (1)

1 International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union 00-413

Abstract: Monolith washcoated catalysts with potential for diesel emission control have been developed. Two types of catalysts have been prepared for further study: (1) MnOx supported on granulated ?-Al2O3, (2) MnOx supported on cordierite monolith washcoated with ?-Al2O3. Both catalysts have been calcined at 500 and 900 �C and subsequently modified by doping with 0.1�1.0 wt% of Pt or Pd. The influence of the concentration of both manganese oxide (0�10 wt%) and noble metals Pt and Pd in the range 0�1.0 wt% on the catalytic activity in methane oxidation has been studied. Comparison of the catalytic activity of MnOx/Al2O3 and MnOx + Pt(Pd)/Al2O3 with that of a standard 1 wt%Pt/Al2O3 catalyst shows the existence of a synergetic effect. This effect is more pronounced for the samples calcined at 900 �C. The developed monolithic catalysts MnOx + Pt(Pd)/Al2O3 demonstrate higher activity and thermal stability (up to 900 �C) compared to the commercial monolithic catalyst (TWC's).
Cite: Yashnik S.A. , Kuznetsov V.V. , Ismagilov Z.R. , Ushakov V.V. , Danchenko N.M. , Denisov S.P.
Development of Monolithic Catalysts with Low Noble Metal Content for Diesel Vehicle Emission Control
Topics in Catalysis. 2004. V.30-31. N1-4. P.293-298. DOI: 10.1023/B:TOCA.0000029765.54179.c9 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published print: Jul 1, 2004
Identifiers:
Web of science: WOS:000222595000047
Scopus: 2-s2.0-3042786272
Elibrary: 13449269
Chemical Abstracts: 2004:603403
Chemical Abstracts (print): 141:178501
OpenAlex: W4252878187
Citing:
DB Citing
Web of science 25
Scopus 23
Elibrary 36
OpenAlex 22
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