Study of Catalysts for Catalytic Burners for Fuel Cell Power Plant Reformers | Sciact - CRIS-система Института катализа

Study of Catalysts for Catalytic Burners for Fuel Cell Power Plant Reformers Научная публикация

Журнал

Korean Journal of Chemical Engineering
ISSN: 0256-1115 , E-ISSN: 1975-7220

Вых. Данные

Год: 2003, Том: 20, Номер: 3, Страницы: 461-467 Страниц : 7 DOI: 10.1007/BF02705548

Ключевые слова

Alumina, Alumina Stabilization by La, Catalytic Burner, Catalytic Combustion, Ce, Fuel Cell, Manganese Oxide Catalysts, Methane, Mg, Pd-Ceria, Reformer

Авторы

Ismagilov Zinfer R. ¹ , Kerzhentsev Mikhail A. ¹ , Sazonov Vladimir A. ¹ , Tsykoza Lidia T. ¹ , Shikina Nadezhda V. ¹ , Kuznetsov Vadim V. ¹ , Ushakov Vladimir A. ¹ , Mishanin Sergey V. ² , Kozhukhar Nikolay G. ² , Russo Gennaro ³ , Deutschmann Olaf ⁴

Организации

1	Boreskov Institute of Catalysis, Pr. Ak. Lavrentieva, 5, Novosibirsk, 630090, Russia
2	Russian Federal Nuclear Center-All-Russian Research Institute of Experimental Physics, Pr. Mira, 37, Sarov, 607190, Russia
3	Instituto di Richerhe sulla Combustione, CNR-Napoli, Piazzale V. Tecchio, 80125, Naples, Italy
4	University of Karlsruhe, ICT, Kaiserstraβe 12, D-76131, Karlsruhe, Germany

Информация о финансировании (2)

1	Международный научно-технический центр	1678
2	International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union	99-1044

Catalytic burners for fuel cell power plant reformers are alternatives to conventional flame burners. Their application is expected to provide uniform temperatures in the reformer, efficient use of low-calorific gaseous by products and reduction of pollutant emissions. For testing in the burners, a series of spherical Pd/CeO2/Al2O3 catalysts were prepared. An optimum concentration of ceria providing the highest thermal stability of catalysts was determined. An effect of catalyst activation in the reaction mixture-1% methane in air was observed. A series of Mn containing oxide catalysts on spherical γ-Al2O3 or (γ+Χ)-Al2O3, both pure and doped with La, Ce and Mg oxides were prepared. The catalysts were characterized by chemical analysis, X-ray phase analysis, BET surface area and activity measurements in methane oxidation. A batch of Mn-Mg-La-Al-O catalyst was prepared for further long-term testing in a model reformer with a catalytic burner. A model reformer with a catalytic burner was designed and fabricated for testing in the composition of the bench-scale Fuel Cell Power Plant. Preliminary testing of this catalyst showed that it provided complete methane combustion at the specified operational temperatures over 900 °C.

Ismagilov Z.R. , Kerzhentsev M.A. , Sazonov V.A. , Tsykoza L.T. , Shikina N.V. , Kuznetsov V.V. , Ushakov V.A. , Mishanin S.V. , Kozhukhar N.G. , Russo G. , Deutschmann O.
Study of Catalysts for Catalytic Burners for Fuel Cell Power Plant Reformers
Korean Journal of Chemical Engineering. 2003. V.20. N3. P.461-467. DOI: 10.1007/BF02705548 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	4 сент. 2002 г.
Принята к публикации:	22 нояб. 2002 г.
Опубликована в печати:	1 мая 2003 г.

Web of science:	WOS:000183246200008
Scopus:	2-s2.0-0042243491
РИНЦ:	13428954
Chemical Abstracts:	2003:572058
Chemical Abstracts (print):	139:294399
OpenAlex:	W2138967413

БД	Цитирований
Web of science	18
Scopus	14
РИНЦ	19
OpenAlex	18