Structure and Electrical Conductivity of Nitrogen-Doped Carbon Nanofibers | Sciact - CRIS-система Института катализа

Structure and Electrical Conductivity of Nitrogen-Doped Carbon Nanofibers Научная публикация

Журнал

Carbon
ISSN: 0008-6223 , E-ISSN: 1873-3891

Вых. Данные

Год: 2009, Том: 47, Номер: 8, Страницы: 1922-1929 Страниц : 8 DOI: 10.1016/j.carbon.2009.02.034

Ключевые слова

Concentration (process); Doping (additives); Electric conductivity; Ethylene; Fourier transform infrared spectroscopy; Graphite; Nitrogen

Авторы

Ismagilov Zinfer R. ¹ , Shalagina Anastasia E. ¹ , Podyacheva Olga Yu. ¹ , Ischenko Arkady V. ¹ , Kibis Lidiya S. ¹ , Boronin Andrey I. ¹ , Chesalov Yury A. ¹ , Kochubey Dmitry I. ¹ , Romanenko Anatoly I. ^2,3 , Anikeeva Olga B. ^2,3 , Buryakov Timofey I. ^2,3 , Tkachev Evgeniy N. ^2,3

Организации

1	Boreskov Institute of Catalysis, Avenue Lavrentyeva, 5 630090 Novosibirsk, Russia
2	Nikolaev Institute of Inorganic Chemistry, Pr. Akad. Lavrentieva 3, Novosibirsk 630090, Russia
3	Novosibirsk State University, Pirogova St. 2, Novosibirsk 630090, Russia

Информация о финансировании (4)

1	Сибирское отделение Российской академии наук	88
2	Министерство образования и науки Российской Федерации	2.1.1/410
3	Президиум РАН	27.58
4	International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union	05-1000005-7726

The effect of nitrogen concentration in carbon nanofibers (CNFs) on the structural and electrical properties of the carbon material was studied. CNFs with nitrogen concentration varied from 0 to 8.2 wt.% (N-CNFs) with “herringbone” structure were prepared by decomposition of ethylene and ethylene mixture with ammonia over 65Ni–25Cu–10Al2O3 (wt.%) catalyst at 823 K. Detailed investigation of the CNFs and N-CNFs by XPS, FTIR and Raman spectroscopy showed that the nitrogen introduction in carbon material distorts the graphite-like lattice and increases the structure defectiveness. Both effects become more significant as the nitrogen concentration in N-CNFs grows. The electrical conductivity of N-CNFs with different nitrogen concentrations is caused by the competition of the nanofiber graphite-like structure disordering after introduction of nitrogen atoms and doping of an additional electron into the delocalized π-system of the graphite-like material. As a result, the maximum electrical conductivity among the samples studied was observed at nitrogen concentration in N-CNFs equal to 3.1 wt.%.

Ismagilov Z.R. , Shalagina A.E. , Podyacheva O.Y. , Ischenko A.V. , Kibis L.S. , Boronin A.I. , Chesalov Y.A. , Kochubey D.I. , Romanenko A.I. , Anikeeva O.B. , Buryakov T.I. , Tkachev E.N.
Structure and Electrical Conductivity of Nitrogen-Doped Carbon Nanofibers
Carbon. 2009. V.47. N8. P.1922-1929. DOI: 10.1016/j.carbon.2009.02.034 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	17 окт. 2008 г.
Принята к публикации:	19 февр. 2009 г.
Опубликована online:	24 мар. 2009 г.
Опубликована в печати:	1 июл. 2009 г.

Web of science:	WOS:000266855800006
Scopus:	2-s2.0-67349183202
РИНЦ:	13613815
Chemical Abstracts:	2009:607176
Chemical Abstracts (print):	152:180893
OpenAlex:	W2020685650

БД	Цитирований
Web of science	354
Scopus	366
РИНЦ	371
OpenAlex	358