Catalytic Asymmetric Oxidations Using Molecular Oxygen Review
| Journal |
Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837 |
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| Output data | Year: 2018, Volume: 87, Number: 9, Pages: 821-830 Pages count : 10 DOI: 10.1070/rcr4825 | ||||
| Tags | Enantioselective alpha-hydroxylation; ketoiminato manganese(III) complexes; phase-transfer catalysts; aerobic epoxidation; unfunctionalized olefins; efficient catalysts; ketones; cyclobutanones; oxindoles; sulfides | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | ГЗ-2017-2020 |
| 2 | Russian Foundation for Basic Research | 16-29-10666 |
Abstract:
Catalytic enantioselective oxygen transfer reactions have been a long-standing goal of synthetic chemistry. The use of molecular oxygen in these oxidations has engaged significant research efforts for decades. The present review considers the state of the art of aerobic asymmetric oxidations mediated by chiral organocatalysts and transition metal catalysts, occurring with formation of new C–O bonds, i.e. oxygenations. The milestones and limitations of existing approaches are discussed, with focus on catalyst design and catalytic performance.
Cite:
Ottenbacher R.V.
, Talsi E.P.
, Bryliakov K.P.
Catalytic Asymmetric Oxidations Using Molecular Oxygen
Russian Chemical Reviews. 2018. V.87. N9. P.821-830. DOI: 10.1070/rcr4825 WOS Scopus РИНЦ OpenAlex AN
Catalytic Asymmetric Oxidations Using Molecular Oxygen
Russian Chemical Reviews. 2018. V.87. N9. P.821-830. DOI: 10.1070/rcr4825 WOS Scopus РИНЦ OpenAlex AN
Original:
Ottenbacher R.V.
, Talsi E.P.
, Bryliakov K.P.
Catalytic Asymmetric Oxidations Using Molecular Oxygen
Russian Chemical Reviews. 2018. V.87. N9. P.821-830. DOI: 10.1070/rcr4825 WOS Scopus РИНЦ OpenAlex AN
Catalytic Asymmetric Oxidations Using Molecular Oxygen
Russian Chemical Reviews. 2018. V.87. N9. P.821-830. DOI: 10.1070/rcr4825 WOS Scopus РИНЦ OpenAlex AN
Dates:
| Submitted: | Mar 27, 2018 |
| Published online: | Sep 3, 2018 |
| Published print: | Sep 30, 2018 |
Identifiers:
| ≡ Web of science: | WOS:000443383600001 |
| ≡ Scopus: | 2-s2.0-85052848680 |
| ≡ Elibrary: | 35268633 |
| ≡ OpenAlex: | W2806733926 |
| ≡ Chemical Abstracts: | 2018:2306610 |