Bi(III) Immobilization Inside MIL-101: Enhanced Photocatalytic Performance | Sciact - CRIS-система Института катализа

Bi(III) Immobilization Inside MIL-101: Enhanced Photocatalytic Performance Научная публикация

Журнал

New Journal of Chemistry
ISSN: 1144-0546 , E-ISSN: 1369-9261

Вых. Данные

Год: 2017, Том: 41, Номер: 6, Страницы: 2255-2260 Страниц : 6 DOI: 10.1039/c6nj03482a

Ключевые слова

METAL-ORGANIC FRAMEWORKS; VISIBLE-LIGHT; HETEROGENEOUS CATALYSTS; DYE DEGRADATION; WATER-TREATMENT; BIOX X; COMPOSITE; NANOPARTICLES; COMPLEXES; LIGAND

Авторы

Kovalenko Konstantin A. ^1,2 , Ruban Natalia V. ² , Adonin Sergey A. ^1,2 , Korneev Denis V. ³ , Erenburg Simon B. ^1,4 , Trubina Svetlana V. ¹ , Kvashnina Kristina ^5,6 , Sokolov Maxim N. ^1,7 , Fedin Vladimir P. ^1,2

Организации

1	Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Av., 630090 Novosibirsk, Russian Federation
2	Novosibirsk State University, 2 Pirogova Street, 630090 Novosibirsk, Russian Federation
3	State Research Centre for Virology and Biotechnology ‘‘Vector’’, 630559 Koltsovo, Novosibirsk Region, Russian Federation
4	Budker Institute of Nuclear Physics SB RAS, 11 Akad. Lavrentiev Av., 630090 Novosibirsk, Russian Federation
5	European Synchrotron Radiation Facility, BP 220, 38043, Grenoble Cedex, France
6	Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Resource Ecology, P.O. Box 510119, 01314, Dresden, Germany
7	Kazan Federal University, Alexander Butlerov Institute of Chemistry, Lobachevskogo Street 1/29, 420008, Kazan, Russian Federation

Информация о финансировании (1)

Российский научный фонд

14-23-00013 (116011510036)

A novel hybrid material Bi(III)@MIL-101 (Bi(III) = Bi-containing oxoclusters and MIL-101 = chromium(III) oxoterephthalate) was obtained by the intra-pore hydrolysis of guest bismuth(III) chloride in ammonia solution. This compound was characterized by chemical analysis, powder X-ray diffraction, nitrogen sorption and TEM techniques. According to the obtained data all Bi species are located only inside the matrix. The framework structure remains intact during all synthetic operations. The chemical nature of Bi(III)-containing clusters inside the MIL-101 matrix was suggested based on the EXAFS study. The catalytic activity of Bi(III)@MIL-101 in photodegradation of methyl red (MR) has been tested. The introduction of Bi(III)-species inside MIL-101 significantly increases the photocatalytic performance in comparison with layered BiOCl which was obtained under the same synthetic conditions without MIL-101.

Kovalenko K.A. , Ruban N.V. , Adonin S.A. , Korneev D.V. , Erenburg S.B. , Trubina S.V. , Kvashnina K. , Sokolov M.N. , Fedin V.P.
Bi(III) Immobilization Inside MIL-101: Enhanced Photocatalytic Performance

New Journal of Chemistry. 2017. V.41. N6. P.2255-2260. DOI: 10.1039/c6nj03482a WOS Scopus РИНЦ CAPlusCA OpenAlex

Полный текст от издателя

Поступила в редакцию:	7 нояб. 2016 г.
Принята к публикации:	30 янв. 2017 г.
Опубликована online:	31 янв. 2017 г.
Опубликована в печати:	21 мар. 2017 г.

Web of science:	WOS:000397749000008
Scopus:	2-s2.0-85015386555
РИНЦ:	29490355
Chemical Abstracts:	2017:180275
Chemical Abstracts (print):	166:290932
OpenAlex:	W2582139779

БД	Цитирований
Web of science	8
Scopus	9
OpenAlex	9