Structural and Transport Properties of Neodymium Tungstates Prepared via Mechanochemical Activation Научная публикация
Журнал |
Ceramics International
ISSN: 0272-8842 |
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Вых. Данные | Год: 2019, Том: 45, Номер: 7 (B), Страницы: 9529-9536 Страниц : 8 DOI: 10.1016/j.ceramint.2018.09.277 | ||||||
Ключевые слова | tungstate, synthesis by mechanical activation, structure, proton transport | ||||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | Российский научный фонд | 16-13-00112 |
2 | Федеральное агентство научных организаций России | 0303-2016-0013 |
Реферат:
Nd5.5WO11.25-δ, (Nd5/6La1/6)5.5WO11.25-δ and Nd5.5W0.5Mo0.5O11.25-δ mixed oxides have been prepared using mechanochemical activation (MA) of Nd2O3-WO3, Nd2O3-La2O3-WO3, Nd2O3-MoO3-WO3 mixtures in a high-power planetary ball mill. Genesis of these tungstates structural properties was studied by XRD, SEM, TEM with EDX analysis, 1H NMR, IR and Raman spectroscopy. X-ray diffraction has revealed that MA results in formation of a pure fluorite structure already after milling. High-density ceramic pellets have been obtained after sintering at 1350 °C. Transport properties of Nd5.5WO11.25-δ mixed oxide were improved by the partial substitution of Nd with La in (Nd5/6La1/6)5.5WO11.25-δ and W with Mo in Nd5.5W0.5Mo0.5O11.25-δ samples. For all samples the electrical conductivity values measured in a humid atmosphere (up to ~ 10-3 S/cm at 550 °C) exceed those measured in a dry atmosphere indicating the proton character of conductivity.
Библиографическая ссылка:
Bespalko Y.
, Eremeev N.
, Skryabin P.
, Krieger T.
, Chesalov Y.
, Lapina O.
, Khabibulin D.
, Ulihin A.
, Uvarov N.
, Sadykov V.
Structural and Transport Properties of Neodymium Tungstates Prepared via Mechanochemical Activation
Ceramics International. 2019. V.45. N7 (B). P.9529-9536. DOI: 10.1016/j.ceramint.2018.09.277 WOS Scopus РИНЦ CAPlus OpenAlex
Structural and Transport Properties of Neodymium Tungstates Prepared via Mechanochemical Activation
Ceramics International. 2019. V.45. N7 (B). P.9529-9536. DOI: 10.1016/j.ceramint.2018.09.277 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: | 29 июл. 2018 г. |
Принята к публикации: | 28 сент. 2018 г. |
Опубликована online: | 1 окт. 2018 г. |
Опубликована в печати: | 1 мая 2019 г. |
Идентификаторы БД:
Web of science: | WOS:000463688400030 |
Scopus: | 2-s2.0-85054523703 |
РИНЦ: | 38619371 |
Chemical Abstracts: | 2018:1865322 |
OpenAlex: | W2895715635 |