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Hydrocracking of Vacuum Gas Oil over NiMo/zeolite-Al2O3: Influence of Zeolite Properties Full article

Journal Fuel
ISSN: 0016-2361 , E-ISSN: 1873-7153
Output data Year: 2019, Volume: 237, Pages: 178-190 Pages count : 13 DOI: 10.1016/j.fuel.2018.10.012
Tags Catalyst, Hydrocracking, Micro-mesoporous zeolite Y, Recrystallization, Vacuum gas oil, Zeolite beta
Authors Dik P.P. 1 , Danilova I.G. 1 , Golubev I.S. 1 , Kazakov M.O. 1 , Nadeina K.A. 1 , Budukva S.V. 1 , Pereyma V.Yu. 1 , Klimov O.V. 1 , Prosvirin I.P. 1 , Gerasimov E.Yu. 1 , Bok T.O. 3 , Dobryakova I.V. 2 , Knyazeva E.E. 2,3 , Ivanova I.I. 2,3 , Noskov A.S. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva 5, 630090 Novosibirsk, Russia
2 Department of Chemistry, Moscow State University, Lenin Hills 1/3, 119991 Moscow, Russia
3 A.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninskiy Prospect 29, 119991 Moscow, Russia

Funding (2)

1 Federal Agency for Scientific Organizations 0303-2016-0010
2 Federal Agency for Scientific Organizations

Abstract: Hydrocracking of vacuum gas oil has been studied over NiMo/zeolite-Al2O3 catalysts. Three different zeolites have been used for catalysts preparation: zeolites Beta (BEA) and Y (FAU) having small crystal size and zeolite Y modified by recrystallization (RFAU). HRTEM, low-temperature N2 adsorption, FTIR of adsorbed CO and TPD-NH3 showed that zeolites had different crystal sizes, mesopore volume, strength and concentration of acid sites. Sulfide active component particles have been revealed to be similar in all catalysts by HRTEM and XPS. NiMo/BEA catalyst having zeolite with the smallest average particle size and the highest concentration of Brønsted acid sites (BAS) demonstrated the highest hydrocracking activity. Selectivity to middle distillates decreased in the following order: NiMo/FAU > NiMo/RFAU > NiMo/BEA. This effect is accounted for by optimal zeolite acidity and improved availability of the acid sites for bulky molecules of the heavy feedstock.
Cite: Dik P.P. , Danilova I.G. , Golubev I.S. , Kazakov M.O. , Nadeina K.A. , Budukva S.V. , Pereyma V.Y. , Klimov O.V. , Prosvirin I.P. , Gerasimov E.Y. , Bok T.O. , Dobryakova I.V. , Knyazeva E.E. , Ivanova I.I. , Noskov A.S.
Hydrocracking of Vacuum Gas Oil over NiMo/zeolite-Al2O3: Influence of Zeolite Properties
Fuel. 2019. V.237. P.178-190. DOI: 10.1016/j.fuel.2018.10.012 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Mar 17, 2018
Accepted: Oct 1, 2018
Published online: Oct 5, 2018
Published print: Feb 1, 2019
Identifiers:
Web of science: WOS:000448573200018
Scopus: 2-s2.0-85054312497
Elibrary: 38646171
Chemical Abstracts: 2018:1865469
Chemical Abstracts (print): 169:539685
OpenAlex: W2895565557
Citing:
DB Citing
Scopus 68
Web of science 58
Elibrary 64
OpenAlex 70
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