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Effects Arising from the Replacement of Aprotic Dipolar Solvents with Ionic Liquids in the Nickel-Catalyzed Reduction of Aryl Chlorides Научная публикация

Журнал Molecular Catalysis
ISSN: 2468-8231
Вых. Данные Год: 2018, Том: 461, Страницы: 19-25 Страниц : 7 DOI: 10.1016/j.mcat.2018.09.022
Ключевые слова Homocoupling, Hydrodehalogenation, Aryl chlorides, Ionic liquid, Zinc, Nickel complexes
Авторы Prikhod’ko S.A. 1,2 , Popov A.G. 1,2 , Adonin N.Yu. 1,2
Организации
1 G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Prosp. Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2 Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk, Russian Federation

Информация о финансировании (1)

1 Федеральное агентство научных организаций России 0303-2016-0007

Реферат: In the work on the example of liquid-phase catalytic processes of the aromatic CCl bonds activation occurring in the presence of nickel complexes under reducing conditions the main effects arising from the replacement of aprotic dipolar solvents with ionic liquids are analyzed. The features of the nickel-catalyzed reaction of aryl chlorides, related to the nature of the anion and cation of the ionic liquid, were observed. It was shown that a high concentration of cations and anions in the ionic liquid affects the process of reduction of the nickel complex to the catalytically active state. In addition, the presence of a reactive hydrogen atom in the imidazolium cation of ionic liquid causes the process of hydrodechlorination of aryl chlorides.
Библиографическая ссылка: Prikhod’ko S.A. , Popov A.G. , Adonin N.Y.
Effects Arising from the Replacement of Aprotic Dipolar Solvents with Ionic Liquids in the Nickel-Catalyzed Reduction of Aryl Chlorides
Molecular Catalysis. 2018. V.461. P.19-25. DOI: 10.1016/j.mcat.2018.09.022 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 28 июн. 2018 г.
Принята к публикации: 30 сент. 2018 г.
Опубликована online: 10 окт. 2018 г.
Опубликована в печати: 1 дек. 2018 г.
Идентификаторы БД:
Web of science: WOS:000450383700003
Scopus: 2-s2.0-85054458060
РИНЦ: 38618358
Chemical Abstracts: 2019:573415
Chemical Abstracts (print): 170:477382
OpenAlex: W2898042497
Цитирование в БД:
БД Цитирований
Scopus 13
Web of science 12
РИНЦ 12
OpenAlex 14
Альметрики: