Cooperative Effect of Metal and Acid Sites of Supported Ni2P Catalysts in Methyl Palmitate Hydrodeoxygenation | Sciact - CRIS-system of Boreskov Institute of Catalysis

Cooperative Effect of Metal and Acid Sites of Supported Ni2P Catalysts in Methyl Palmitate Hydrodeoxygenation Conference Abstracts

Conference

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence

Source

13th European Congress on Catalysis
Compilation, 2017.

Output data

Year: 2017, Article number : SS17.10, Pages count : 2

Authors

Deliy I. ^1,2 , Shamanaev I.V. ¹ , Antonov I.M. ^1,2 , Pakharukova V.P. ^1,2 , Gerasimov E.Y. ^1,2 , Yakovlev I.V. ^1,2 , Andreev A.S. ¹ , Lapina O.B. ¹ , Bukhtiyarova G.A. ¹

Affiliations

1	Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Novosibirsk, 630090, Russia

Funding (1)

Federal Agency for Scientific Organizations

0303-2016-0012 (V.47.1.4.)

It was reported the effective approach to enhancing catalytic activity of supported nickel phosphide catalysts for methyl palmitate hydrodeoxygenation by combination of metal and acid sites in catalytic systems. The catalytic activities of NixPy/SiO2 catalysts depend on the composition of the nickel phosphide phase and quantity of surface acid POx groups identified by 31P MAS NMR. The most active SiO2-supported nickel phosphide catalysts have been formed using phosphite type precursor and Ni/P initial molar ratios lower than 1.0. Moreover, the cooperative effect was observed in methyl palmitate and intermediates transformations over physical mixture of Ni2P/SiO2 and γ-Al2O3 leading to the significant increase in catalytic activity.

Deliy I. , Shamanaev I.V. , Antonov I.M. , Pakharukova V.P. , Gerasimov E.Y. , Yakovlev I.V. , Andreev A.S. , Lapina O.B. , Bukhtiyarova G.A.
Cooperative Effect of Metal and Acid Sites of Supported Ni2P Catalysts in Methyl Palmitate Hydrodeoxygenation
In compilation 13th European Congress on Catalysis. 2017. – C.213-214.

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