Interaction of Vanadium Containing Catalysts with Microwaves and Their Activation in Oxidative Dehydrogenation of Ethane | Sciact - CRIS-система Института катализа

Interaction of Vanadium Containing Catalysts with Microwaves and Their Activation in Oxidative Dehydrogenation of Ethane Научная публикация

Конференция

8th European Workshop Meeting on Selective Oxidation
26-31 авг. 2007 , Turku

Журнал

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Вых. Данные

Год: 2009, Том: 141, Номер: 3-4, Страницы: 300-305 Страниц : 6 DOI: 10.1016/j.cattod.2008.04.021

Ключевые слова

Antimony, Catalyst, Dehydrogenation, Ethane, Microwave activation, Molybdenum, Niobium, Vanadium

Авторы

Sinev Ilia ¹ , Kardash Tatiana ² , Kramareva Natalia ¹ , Sinev Mikhail ³ , Tkachenko Olga ¹ , Kucherov Alexei ¹ , Kustov Leonid M. ¹

Организации

1	Zelinsky Institute of Organic Chemistry, R.A.S., Moscow 119991, Russia
2	Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
3	Semenov Institute of Chemical Physics, R.A.S., Moscow 119991, Russia

Информация о финансировании (1)

Haldor Topsoe (Denmark)

Microwave (MW)-activated oxidative dehydrogenation of ethane is studied using kinetic approach. It consists in the comparison of kinetic dependencies (shape of kinetic equations, “selectivity or yield vs. conversion” curves) and apparent parameters (activation energies) obtained in thermal and MW modes. In the case of VMo and VMoNb oxides a distinct difference between ethane yields was observed at given conversion of limiting reactant (oxygen). It was proven by X-ray diffraction that MW activation changes the catalyst microstructure forming phase distribution different from that formed under a conventional heating and thus changing catalytic behavior of VMo and VMoNb oxides.

Sinev I. , Kardash T. , Kramareva N. , Sinev M. , Tkachenko O. , Kucherov A. , Kustov L.M.
Interaction of Vanadium Containing Catalysts with Microwaves and Their Activation in Oxidative Dehydrogenation of Ethane
Catalysis Today. 2009. V.141. N3-4. P.300-305. DOI: 10.1016/j.cattod.2008.04.021 WOS Scopus РИНЦ CAPlusCA OpenAlex

Опубликована online:	16 июн. 2008 г.
Опубликована в печати:	30 мар. 2009 г.

Web of science:	WOS:000264816500010
Scopus:	2-s2.0-60949106658
РИНЦ:	13600616
Chemical Abstracts:	2009:252040
Chemical Abstracts (print):	150:473183
OpenAlex:	W2032088186

БД	Цитирований
Web of science	15
Scopus	18
РИНЦ	15
OpenAlex	22