Sciact
  • EN
  • RU

Analysis of the Facilities of the NMR in Study of the Geometry of Paramagnetic Metal Complexes in Solutions Тезисы доклада

Конференция XXth Congress AMPERE
21-26 авг. 1978 , Tallinn
Сборник Magnetic Resonance and Related Phenomena: Proceedings of the XXth Congress AMPERE, Tallinn, August 21–26, 1978
Сборник, Springer. Berlin, Heidelberg.1979. 606 c. ISBN 9783642813467;9783642813443.
Вых. Данные Год: 1979, Страницы: 503-503 Страниц : 1 DOI: 10.1007/978-3-642-81344-3_439
Ключевые слова Paramagnetic Shift; Base Heterocycle; Artificial Error;Isotropic Complex; Density Delocalization
Авторы Nekipelov V.M. 1 , Zamaraev K.I. 1
Организации
1 Institute of Catalysis of the Siberian Branch of the Academy of Sciences of the USSR, Novosibirsk, USSR

Реферат: Using complexes of bisacetylacetonato Co(II) and Ni(II) with pyridine type ligands as models, it was shown that geometric parameters of paramagnetic metal complexes may be calculated using a set of equations, left parts of which are experimental NMR data (chemical shifts and relaxation rates) and right ones — theoretical expressions for them. The validity of the proposed procedure is confirmed by the existence of solutions for sets with the number of equations exceeding the number of the unknown parameters as well as by a rather good accuracy (about 5%) of the calculated values and their good agreement with the corresponding X-ray data.
Библиографическая ссылка: Nekipelov V.M. , Zamaraev K.I.
Analysis of the Facilities of the NMR in Study of the Geometry of Paramagnetic Metal Complexes in Solutions
В сборнике Magnetic Resonance and Related Phenomena: Proceedings of the XXth Congress AMPERE, Tallinn, August 21–26, 1978. – Springer., 1979. – C.503-503. – ISBN 9783642813467;9783642813443. DOI: 10.1007/978-3-642-81344-3_439CAPlusCA OpenAlex
Идентификаторы БД:
Chemical Abstracts: 1980:523201
Chemical Abstracts (print): 93:123201
OpenAlex: W2485140575
Цитирование в БД: Пока нет цитирований
Альметрики: