Homogeneous Catalysts for Ethylene Polymerization Based on bis(Imino)pyridine Complexes of Iron, Cobalt, Vanadium and Chromium Full article
| Conference |
III International Conference "Catalysis: fundamentals and application" 04-08 Jul 2007 , Novosibirsk |
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| Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Output data | Year: 2009, Volume: 144, Number: 3-4, Pages: 334-340 Pages count : 7 DOI: 10.1016/j.cattod.2009.01.022 | ||
| Tags | 2,6-Bis(imino)pyridine complexes of iron(II), Chromium(III) and vanadium(III), Cobalt(II), Ethylene polymerization, Molecular weight distribution, Polyethylene | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 06-03-32700 |
Abstract:
Results of a comparative study of ethylene polymerization activity and the structure of polyethylene (PE) produced over homogeneous catalysts based on bis(imino)pyridine complexes with close ligand frameworks and different transition metal centers (Fe(II), Co(II), Cr(III) and V(III)) are reported. The effects of the activator nature and polymerization conditions on the activity of these complexes and the resulting PE structure (molecular weight, molecular weight distribution, content of methyl and vinyl groups) have been studied. The experimental data obtained under comparable conditions demonstrate a pronounced effect of transition metal center on the catalytic properties of bis(imino)pyridine complexes (polymerization activity, copolymerization reactivity, thermal stability, PE structure, composition of optimal activator, formation of single-site or multiple-site catalytic system).
Cite:
Semikolenova N.V.
, Zakharov V.A.
, Echevskaja L.G.
, Matsko M.A.
, Bryliakov K.P.
, Talsi E.P.
Homogeneous Catalysts for Ethylene Polymerization Based on bis(Imino)pyridine Complexes of Iron, Cobalt, Vanadium and Chromium
Catalysis Today. 2009. V.144. N3-4. P.334-340. DOI: 10.1016/j.cattod.2009.01.022 WOS Scopus РИНЦ OpenAlex ANCAN
Homogeneous Catalysts for Ethylene Polymerization Based on bis(Imino)pyridine Complexes of Iron, Cobalt, Vanadium and Chromium
Catalysis Today. 2009. V.144. N3-4. P.334-340. DOI: 10.1016/j.cattod.2009.01.022 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Published online: | Feb 20, 2009 |
| Published print: | Jun 30, 2009 |
Identifiers:
| ≡ Web of science: | WOS:000267409100018 |
| ≡ Scopus: | 2-s2.0-67349099857 |
| ≡ Elibrary: | 13607980 |
| ≡ OpenAlex: | W1965983957 |
| ≡ Chemical Abstracts: | 2009:664151 |
| ≡ Chemical Abstracts (print): | 151:173926 |