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Conversion of Hydrocarbon Fuels to Syngas in a Short Contact Time Catalytic Reactor Full article

Conference III International Conference "Catalysis: fundamentals and application"
04-08 Jul 2007 , Novosibirsk
Journal Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Output data Year: 2009, Volume: 144, Number: 3-4, Pages: 185-200 Pages count : 6 DOI: 10.1016/j.cattod.2009.01.034
Tags Dynamic simulations, Gasoline, Isooctane, Methane, Monolith reactor, Radial-flow reactor, Syngas formation, Thermodynamics
Authors Bobrova L. 1 , Vernikovskaya N. 1 , Sadykov V. 1
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russia

Abstract: Some results of the theoretical and experimental research on the oxidative production of syngas from hydrocarbon fuels in catalytic reactors which operate at high temperatures and short contact times are presented. Pilot scale tests of the partial oxidation of methane, isooctane and gasoline have been carried out in nearly adiabatic conditions on structured catalysts developed at the Boreskov Institute of Catalysis and characterized by a low (≤0.5 wt./wt.%) content of noble metals. High yield of syngas and stable performance of the catalysts were revealed in the experiments. The details of interaction between chemical and physical processes inside adiabatic monolith reactor have been elucidated by mathematical modeling of the partial oxidation reaction on the base of catalyst detailed chemistry. The problems that emerged from the short contact time reactor operating on a pilot scale are also discussed.
Cite: Bobrova L. , Vernikovskaya N. , Sadykov V.
Conversion of Hydrocarbon Fuels to Syngas in a Short Contact Time Catalytic Reactor
Catalysis Today. 2009. V.144. N3-4. P.185-200. DOI: 10.1016/j.cattod.2009.01.034 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Mar 4, 2009
Published print: Jun 30, 2009
Identifiers:
Web of science: WOS:000267409100002
Scopus: 2-s2.0-66349102915
Elibrary: 13613612
Chemical Abstracts: 2009:664135
Chemical Abstracts (print): 151:177141
OpenAlex: W1983714206
Citing:
DB Citing
Web of science 16
Scopus 20
Elibrary 20
OpenAlex 17
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