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Thermal Decomposition in Systems of Acid Zn(II), Co(II), and Ni(II) Maleates with the Formation of Metallic Nanoparticles Научная публикация

Журнал Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X
Вых. Данные Год: 2018, Том: 92, Номер: 11, Страницы: 2247-2252 Страниц : 6 DOI: 10.1134/s003602441811047x
Ключевые слова thermal decomposition, maleate, nanoparticles, transition metals, nanotubes, metal/polymer composites, catalysts, quantum-size effect
Авторы Yudanova L. I. 1 , Logvinenko V. A. 1,2 , Korol’kov I. V. 1,2 , Ishchenko A. V. 2,3 , Rudina N. A. 3
Организации
1 Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch, Novosibirsk, 630090 Russia
2 Novosibirsk State University, Novosibirsk, 630090 Russia
3 Boreskov Institute of Catalysis, Russian Academy of Sciences, Siberian Branch, Novosibirsk, 630090 Russia

Реферат: Conditions of synthesis are optimized and XRD and thermoanalytical studies are performed for normal maleate [Zn(H2O)2(C4H2O4)] and acid maleate [Zn(H2O)4(C4H3O4)2], along with acid Co(II)–Zn(II), Ni(II)–Zn(II) maleates. It is shown that when solid solutions thermally decompose in acidic maleate systems, the kinetically less stable component causes the temperature of decomposition of the more stable component to fall. It is established that the solid residue of Zn(II) maleate after heating to 500°C in a He atmosphere is a composite containing Zn oxide whose reduction to metal begins at 675°C. The decomposition of [(Co0.1Zn0.9)(H2O)4(С4H3O4)2] leads to the oozing of metallic cobalt atoms embedded in the channels of the ZnO structure that act as a catalyst for the spontaneous growth of uniform carbon nanotubes on the surface of the composite. After thermal decomposition of the samples in a system of acid Ni(II) maleate–acid Zn(II) maleate, only the bimetallic phase is observed in the composites, and there is no zinc oxide.
Библиографическая ссылка: Yudanova L.I. , Logvinenko V.A. , Korol’kov I.V. , Ishchenko A.V. , Rudina N.A.
Thermal Decomposition in Systems of Acid Zn(II), Co(II), and Ni(II) Maleates with the Formation of Metallic Nanoparticles
Russian Journal of Physical Chemistry A. 2018. V.92. N11. P.2247-2252. DOI: 10.1134/s003602441811047x WOS Scopus РИНЦ CAPlus OpenAlex
Оригинальная: Юданова Л.И. , Логвиненко В.А. , Корольков И.В. , Ищенко А.В. , Рудина Н.А.
Особенности термического разложения в системах кислых малеатов Zn(II), Co(II), Ni(II) с образованием металлических наночастиц
Журнал физической химии. 2018. Т.92. №11. С.1753-1759. DOI: 10.1134/s004445371811047x РИНЦ OpenAlex
Даты:
Поступила в редакцию: 19 янв. 2018 г.
Опубликована online: 16 окт. 2018 г.
Опубликована в печати: 1 нояб. 2018 г.
Идентификаторы БД:
Web of science: WOS:000447676200027
Scopus: 2-s2.0-85055094474
РИНЦ: 38630937
Chemical Abstracts: 2018:1943010
OpenAlex: W2897479960
Цитирование в БД:
БД Цитирований
Web of science 10
Scopus 10
РИНЦ 12
OpenAlex 11
Альметрики: