Effect of Ce Cations on the Crystallite Size and Pore Structure Genesis in Nanostructured Rutile After Calcination Научная публикация
Журнал |
Наносистемы: физика, химия, математика = Nanosystems: physics, chemistry, mathematics
ISSN: 2220-8054 , E-ISSN: 2305-7971 |
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Вых. Данные | Год: 2018, Том: 9, Номер: 5, Страницы: 688-695 Страниц : 8 DOI: 10.17586/2220-8054-2018-9-5-688-695 | ||||
Ключевые слова | titanium dioxide, nanostructured rutile, hierarchical architecture, porous structure, thermal treatment | ||||
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Организации |
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Информация о финансировании (1)
1 | Федеральное агентство научных организаций России | 0303-2016-0004 |
Реферат:
A method for the low-temperature synthesis of titania with the 3D rutile nanostructure was developed, and the effect of introduced cerium ions on the thermal stability of the material was studied. According to XRD, TEM, Raman spectroscopy and BET data, the introduction of 3 – 10 wt.% Ce into the rutile matrix decreases the growth of nanorutile crystallites under the action of high temperatures ranging from 300 – 1000 °C and provides the formation of a more porous structure in comparison with unmodified samples. Cerium cations are stabilized in the region of interblock boundaries or in the structural defects of rutile TiO2 and are released as the bulk CeO2 phase only at 1000 °C, which does not exert a stabilizing effect at this temperature.
Библиографическая ссылка:
Shikina N.V.
, Bessudnova E.V.
, Ushakov V.A.
, Nikitin A.P.
, Mel’gunov M.S.
, Ishchenko A.V.
, Ismagilov Z.R.
Effect of Ce Cations on the Crystallite Size and Pore Structure Genesis in Nanostructured Rutile After Calcination
Наносистемы: физика, химия, математика = Nanosystems: physics, chemistry, mathematics. 2018.
V.9. N5. P.688-695. DOI: 10.17586/2220-8054-2018-9-5-688-695
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Effect of Ce Cations on the Crystallite Size and Pore Structure Genesis in Nanostructured Rutile After Calcination
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Полный текст от издателя
Даты:
Поступила в редакцию: | 31 мая 2018 г. |
Принята к публикации: | 3 авг. 2018 г. |
Опубликована в печати: | 31 окт. 2018 г. |
Опубликована online: | 31 окт. 2018 г. |
Идентификаторы БД:
Web of science: | WOS:000454046400013 |
Russian Science Citation Index (RSCI): | RSCI:36414514 |
РИНЦ: | 36414514 |
Chemical Abstracts: | 2019:1976092 |
OpenAlex: | W2899322754 |