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Insights into the Reactivity of La1-xSrxMnO3 Mixed Oxides in Catalytic Methane Combustion Conference Abstracts

Conference 9th Natural Gas Conversion Symposium
30 May - 3 Jun 2010 , Lyon
Source 9th Novel Gas Conversion Symposium (NGCS9), Lyon - France, May 30th - June 3rd 2010 : Book of Abstracts
Compilation, 2010. 266 c.
Output data Year: 2011, Article number : P349 (450), Pages count : 1
Authors Ivanov D. 1 , Pinaeva L. 1 , Sadovskaya E. 1 , Isupova L. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, pr. Acad. Lavrentieva 5, 630090 Novosibirsk, Russia

Abstract: Investigation of oxygen isotope exchange revealed a clear view on the mechanism of oxygen mobility in La1-xSrxMn(Fe)O3 mixed oxides and enabled to establish a correlation between the oxygen mobility and catalytic activity in methane combustion. Sr promotion resulted in the appearance of the fast pathway of oxygen diffusion in the bulk through oxygen vacancies. High reactivity of multiphase samples correlated well with the appearance of highly defective layer-structured (La1-ySry)2Mn(Fe)O4 perovskites on the surface which makes layer-structured phases promising catalysts for methane combustion.
Cite: Ivanov D. , Pinaeva L. , Sadovskaya E. , Isupova L.
Insights into the Reactivity of La1-xSrxMnO3 Mixed Oxides in Catalytic Methane Combustion
In compilation 9th Novel Gas Conversion Symposium (NGCS9), Lyon - France, May 30th - June 3rd 2010 : Book of Abstracts. 2011. – C.228.
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