Superelectrophilic Activation of 1-Nitronaphthalene in the Presence of Aluminum Chloride. Reactions with Benzene and Cyclohexane Full article
| Journal |
Organic and Biomolecular Chemistry
ISSN: 1477-0520 , E-ISSN: 1477-0539 |
||||||
|---|---|---|---|---|---|---|---|
| Output data | Year: 2018, Volume: 16, Number: 47, Pages: 9129-9132 Pages count : 4 DOI: 10.1039/c8ob02653j | ||||||
| Tags | Benzene; Chlorine compounds; Coordination reactions; Cyclohexane | ||||||
| Authors |
|
||||||
| Affiliations |
|
Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0006 (V.44.1.6) |
| 2 | Russian Foundation for Basic Research | 17-03-00564 (АААА-А17-117040310053-5) |
Abstract:
1-Nitronaphthalene smoothly reacts with benzene and undergoes selective reduction with cyclohexane in the presence of aluminum chloride to give 2,4,4-triphenyl-3,4-dihydronaphthalen-1(2H)-one oxime and 5,6,7,8-tetrahydro-1-naphthylamine, respectively. The mechanistic aspects of these and related reactions are discussed on the basis of DFT, providing insight into the protonation behavior of 1-nitronaphthalene coordinated to AlCl3.
Cite:
Zhu Z.
, Genaev A.M.
, Salnikov G.E.
, Koltunov K.Y.
Superelectrophilic Activation of 1-Nitronaphthalene in the Presence of Aluminum Chloride. Reactions with Benzene and Cyclohexane
Organic and Biomolecular Chemistry. 2018. V.16. N47. P.9129-9132. DOI: 10.1039/c8ob02653j WOS Scopus РИНЦ AN OpenAlex
Superelectrophilic Activation of 1-Nitronaphthalene in the Presence of Aluminum Chloride. Reactions with Benzene and Cyclohexane
Organic and Biomolecular Chemistry. 2018. V.16. N47. P.9129-9132. DOI: 10.1039/c8ob02653j WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Oct 26, 2018 |
| Accepted: | Nov 14, 2018 |
| Published online: | Nov 21, 2018 |
| Published print: | Dec 1, 2018 |
Identifiers:
| Web of science: | WOS:000452321100004 |
| Scopus: | 2-s2.0-85058193646 |
| Elibrary: | 38678698 |
| Chemical Abstracts: | 2018:2308769 |
| OpenAlex: | W2901795858 |