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Crystal Structures of Uranyl Complexes with Isobutyrate and Isovalerate Anions Научная публикация

Журнал Dalton Transactions
ISSN: 1477-9226 , E-ISSN: 1477-9234
Вых. Данные Год: 2018, Том: 47, Номер: 6, Страницы: 1849-1856 Страниц : 8 DOI: 10.1039/c7dt04042c
Ключевые слова X-RAY-DIFFRACTION; NEUTRON-DIFFRACTION; HYDROGEN-BOND; CS; REFINEMENT; SPECIATION; DATABASE; IONS; RB
Авторы Savchenkov Anton V. 1 , Vologzhanina Anna V. 2 , Dmitrienko Artem O. 2 , Zubavichus Yan V. 3 , Pushkin Denis V. 1 , Serezhkin Viktor N. 1
Организации
1 Samara National Research University, 443011 Samara, Russian Federation
2 Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
3 National Research Center “Kurchatov Institute”

Информация о финансировании (2)

1 Министерство образования и науки Российской Федерации 14.619.21.0007 (RFMEFI61917X0007)(АААА-А18-118011190114-0)
2 Российский научный фонд 17-73-10117

Реферат: Single crystals of Na[(UO2)(i-C3H7COO)3]·0.7H2O (I), Cs[(UO2)(i-C3H7COO)3] (II) and (NH4)[(UO2)(i-C4H9COO)3] (III) were obtained via isothermal evaporation and their structures were solved using X-ray diffraction techniques. Even though the ligands are branched, bulky and spatial, many carbon and hydrogen atoms are still disordered in these crystal structures at low temperature. A new type of Na coordination is observed for the first time for this family of compounds, proposing high sensitivity of compound I to humidity. Depolymerization of the metal–oxygen frameworks for the new compounds is compared with the known ones. Coordination sequences of sodium/cesium and uranyl complexes with aliphatic monocarboxylate ions are calculated to show different crystal-chemical function of crystallographically independent atoms. As there are analogous compounds to the title ones with straight-chain ligands, such groups of similar compounds with single varying parameters are very advantageous for establishing correlations between composition and crystal structure.
Библиографическая ссылка: Savchenkov A.V. , Vologzhanina A.V. , Dmitrienko A.O. , Zubavichus Y.V. , Pushkin D.V. , Serezhkin V.N.
Crystal Structures of Uranyl Complexes with Isobutyrate and Isovalerate Anions
Dalton Transactions. 2018. V.47. N6. P.1849-1856. DOI: 10.1039/c7dt04042c WOS Scopus РИНЦ CAPlusCA OpenAlex
Файлы: Полный текст от издателя
Даты:
Поступила в редакцию: 27 окт. 2017 г.
Принята к публикации: 25 дек. 2017 г.
Опубликована online: 16 янв. 2018 г.
Опубликована в печати: 14 февр. 2018 г.
Идентификаторы БД:
Web of science: WOS:000424226200015
Scopus: 2-s2.0-85041903835
РИНЦ: 35502123
Chemical Abstracts: 2018:85864
Chemical Abstracts (print): 168:208110
OpenAlex: W2783435088
Цитирование в БД:
БД Цитирований
Web of science 7
Scopus 7
OpenAlex 7
Альметрики: