Ce-Silica Mesoporous SBA-15-Type Materials for Oxidative Catalysis: Synthesis, Characterization, and Catalytic Application | Sciact - CRIS-system of Boreskov Institute of Catalysis

Ce-Silica Mesoporous SBA-15-Type Materials for Oxidative Catalysis: Synthesis, Characterization, and Catalytic Application Full article

Journal

Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875

Output data

Year: 2007, Volume: 317, Number: 1, Pages: 1-10 Pages count : 10 DOI: 10.1016/j.apcata.2006.07.014

Tags

Cerium-containing mesoporous materials; SBA-15; Cyclohexene oxidation; Cyclohexanol oxidation; Hydrogen peroxide

Authors

Timofeeva M.N. ^1,2 , Jhung S.H. ¹ , Hwang Y.K. ¹ , Kim D.K. ¹ , Panchenko V.N. ¹ , Melgunov M.S. ¹ , Chesalov Yu.A. ¹ , Chang J.-S. ¹

Affiliations

1	Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology, P.O. Box 107, Yusung, Daejeon 305-600, South Korea
2	Boreskov Institute of Catalysis SB RAS, Group of stereoselective catalysis, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation

Cerium-containing mesoporous materials have been synthesized by hydrothermal method and characterized by IR, DR-UV–vis and DRIFT spectroscopy, XRD and N2 adsorption methods. It was established that the d100 and unit-cell (a0) parameter increase with the increase of cerium content up to 2% in SBA-15 and then tend to remain the same. According to DR-UV–vis spectroscopic data, an agglomeration of cerium atoms was observed in the form of fine CeO2 crystallites. Important factors affecting the catalytic activity of Ce-SBA-15, namely the effect of cerium content, the state of cerium ions, the state of silanol groups on the surface of Ce-SBA-15, and stability of the catalyst have been studied in the cyclohexanol and cyclohexene oxidation with hydrogen peroxide.

Timofeeva M.N. , Jhung S.H. , Hwang Y.K. , Kim D.K. , Panchenko V.N. , Melgunov M.S. , Chesalov Y.A. , Chang J.-S.
Ce-Silica Mesoporous SBA-15-Type Materials for Oxidative Catalysis: Synthesis, Characterization, and Catalytic Application
Applied Catalysis A: General. 2007. V.317. N1. P.1-10. DOI: 10.1016/j.apcata.2006.07.014 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 3, 2006
Accepted:	Jul 16, 2006
Published online:	Nov 7, 2006
Published print:	Jan 1, 2007

Web of science:	WOS:000243665000001
Scopus:	2-s2.0-33845516460
Elibrary:	31330150
Chemical Abstracts:	2006:1321802
Chemical Abstracts (print):	146:184077
OpenAlex:	W2072314618

DB	Citing
Web of science	92
Scopus	94
OpenAlex	93