Study of Bimetallic Ni-Mo Carbides in Catalytic Hydrogenation of Furfural to Value-Added Chemicals | Sciact - CRIS-system of Boreskov Institute of Catalysis

Study of Bimetallic Ni-Mo Carbides in Catalytic Hydrogenation of Furfural to Value-Added Chemicals Full article

Conference

Recent Advances on Environment, Chemical Engineering and Materials : 2nd International Conference
22-24 Jun 2018 , Sliema

Source

Recent Advances on Environment, Chemical Engineering and Materials
Compilation, 2018. ISBN 978-0-7354-1740-3.

Journal

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Output data

Year: 2018, Volume: 2022, Article number : 020022, Pages count : 6 DOI: 10.1063/1.5060702

Authors

Smirnov Andrey A. ^1,2 , Shilov Ivan N ^1,2 , Bulavchenko Olga A ^1,2 , Yakovlev Vadim A ^1,2

Affiliations

1	Novosibirsk State University, Novosibirsk, Russia
2	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

Funding (1)

The Ministry of Education and Science of the Russian Federation

14.575.21.0171 (RFMEFI57517X0171)

The paper aims to study the effect of the composition of high-percentage carbide Ni-Mo systems modified by SiO2 on their activity and selectivity in the hydrogenation of furfural. The process was carried out in a solution of isopropanol at a temperature of 150 °C and a hydrogen pressure of 6.0 MPa in autoclave reactor. The main hydrogenation products were furfuryl alcohol (FA) and 2-methylfuran (2-MF). The formation of side compounds, such as tetrahydrofurfuryl alcohol and 2-methyltetrahydrofuran, was also observed. According to X-ray analysis, the catalytic systems synthesized using the Pechini method using citric acid and ethylene glycol as the carbon source contain the carbide phases (hex)-Mo2C, (cub)-MoC and Ni2Mo3C. It is shown that carbide content decreases with the amount of nickel in the catalyst, in addition, formation of a Ni-Mo alloy enriched in nickel is observed. It was indicated that a high Ni content increases the yield of by-products. At the same time, catalysts with a high content of carbide phases have a lower activity, but they allow obtaining a 60 mol.% FA yield and up to 29 mol.% of 2-MF.

Smirnov A.A. , Shilov I.N. , Bulavchenko O.A. , Yakovlev V.A.
Study of Bimetallic Ni-Mo Carbides in Catalytic Hydrogenation of Furfural to Value-Added Chemicals
In compilation Recent Advances on Environment, Chemical Engineering and Materials. 2018. – ISBN 978-0-7354-1740-3. DOI: 10.1063/1.5060702 WOS Scopus РИНЦ AN OpenAlex

Full text from publisher

Web of science:	WOS:000481676400022
Scopus:	2-s2.0-85057344539
Elibrary:	38612060
Chemical Abstracts:	2018:2387635
OpenAlex:	W2899752365

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