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Mass Spectral Evaluation of Column Bleeding for Imidazolium-Based Ionic Liquids as GC Liquid Phases Full article

Journal Analytical and Bioanalytical Chemistry
ISSN: 1618-2642 , E-ISSN: 1618-2650
Output data Year: 2012, Volume: 403, Number: 9, Pages: 2673-2682 Pages count : 10 DOI: 10.1007/s00216-012-6020-9
Tags Capillary column, GC/MS, Ionic liquids, MSMS
Authors Shashkov M.V. 1 , Sidelnikov V.N. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS, pr. Lavrentieva 5, 630090, Novosibirsk, Russia

Abstract: Mass spectra were obtained to evaluate the use of numerous single-cation and dicationic ionic liquids as stationary liquid phases in GC/MS at high temperature. Background mass spectra and product ion mass spectra of several ions in the background spectrum were obtained. Fragmentation mechanisms were propounded, including the detailed fragmentation pathway of the 1,2-dimethyl-3-propylimidazole cation. The relation between temperature and the main signals in the mass spectra of ILs was studied.
Cite: Shashkov M.V. , Sidelnikov V.N.
Mass Spectral Evaluation of Column Bleeding for Imidazolium-Based Ionic Liquids as GC Liquid Phases
Analytical and Bioanalytical Chemistry. 2012. V.403. N9. P.2673-2682. DOI: 10.1007/s00216-012-6020-9 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Dates:
Submitted: Feb 7, 2012
Accepted: Apr 3, 2012
Published online: May 10, 2012
Published print: Jul 1, 2012
Identifiers:
Web of science: WOS:000305228600024
Scopus: 2-s2.0-84863785538
Elibrary: 21902398
Chemical Abstracts: 2012:676693
Chemical Abstracts (print): 157:31070
PMID: 22573059
OpenAlex: W2062862569
Citing:
DB Citing
Web of science 17
Scopus 17
Elibrary 17
OpenAlex 21
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