Optical Spectroscopy Methods in the Estimation of the Thermal Stability of Bimetallic Pd Rh/Al2O3 Three-Way Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Optical Spectroscopy Methods in the Estimation of the Thermal Stability of Bimetallic Pd Rh/Al2O3 Three-Way Catalysts Full article

Conference

Eleventh International Congress on Catalysis and Automotive Pollution Control
29-31 Oct 2018 , Brussels

Journal

Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028

Output data

Year: 2019, Volume: 62, Number: 1-4 SI, Pages: 296–304 Pages count : 9 DOI: 10.1007/s11244-018-1112-1

Tags

Three-way catalysts; prompt thermal aging; luminescence spectroscopy; UV-Vis spectroscopy; metal migration

Authors

Stoyanovskii Vladimir O. ¹ , Vedyagin Aleksey A. ^1,2 , Volodin Alexander M. ¹ , Kenzhin Roman M. ¹ , Slavinskaya Elena M. ¹ , Plyusnin Pavel E. ^3,4 , Shubin Yury V. ^3,4

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russian Federation
2	National Research Tomsk Polytechnic University, Tomsk, Russian Federation
3	Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russian Federation
4	National Research University-Novosibirsk State University, Novosibirsk, Russian Federation

Funding (3)

1	Russian Foundation for Basic Research	16-08-01283
2	Federal Agency for Scientific Organizations	0303-2016-0014
3	The Ministry of Education and Science of the Russian Federation	4.5200.2017

A series of three-way catalysts containing palladium and rhodium were prepared by an incipient wetness impregnation of support with aqueous solution of [Pd(NH3)4](NO3)2 and Na3[Rh(NO2)6] compounds. Both pure and La-doped aluminum oxides were used as a support. The catalysts showed very close activity under stoichiometric and reductive conditions, but were different in terms of thermal stability being tested in a prompt thermal aging regime. UV-Vis and luminescence spectroscopies were found to be informative for diagnostics of rhodium and palladium concentration and state, thus giving the possibility to follow the changes taking place with active components (migration, agglomeration, bulk diffusion).

Stoyanovskii V.O. , Vedyagin A.A. , Volodin A.M. , Kenzhin R.M. , Slavinskaya E.M. , Plyusnin P.E. , Shubin Y.V.
Optical Spectroscopy Methods in the Estimation of the Thermal Stability of Bimetallic Pd Rh/Al2O3 Three-Way Catalysts
Topics in Catalysis. 2019. V.62. N1-4 SI. P.296–304. DOI: 10.1007/s11244-018-1112-1 WOS Scopus РИНЦ ANCAN OpenAlex

Published online:	Dec 7, 2018
Published print:	Feb 1, 2019

Web of science:	WOS:000461821000038
Scopus:	2-s2.0-85058086607
Elibrary:	38635115
Chemical Abstracts:	2018:2511124
Chemical Abstracts (print):	172:278091
OpenAlex:	W2903860518

DB	Citing
Scopus	13
Web of science	11
Elibrary	11
OpenAlex	11