Sciact
  • EN
  • RU

Revised Phase Diagram of Li2MoO4-ZnMoO4 System, Crystal Structure and Crystal Growth of Lithium Zinc Molybdate Научная публикация

Журнал Journal of Solid State Chemistry
ISSN: 0022-4596 , E-ISSN: 1095-726X
Вых. Данные Год: 2009, Том: 182, Номер: 7, Страницы: 1935-1943 Страниц : 9 DOI: 10.1016/j.jssc.2009.04.036
Ключевые слова Cation disorder, Crystal growth, Crystal structure, Lithium zinc molybdate, Nonstoichiometry, Physical properties, T-x phase diagram
Авторы Solodovnikov Sergey F. 1,2 , Solodovnikova Zoya A. 1 , Zolotova Evgeniya S. 1 , Yudanova Lyudmila I. 1 , Kardash Tatyana Yu. 3 , Pavlyuk Anatoly A. 1 , Nadolinny Vladimir A. 1
Организации
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Acad. Lavrentiev Ave. 3, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova St. 2, Novosibirsk 630090, Russia
3 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Acad. Lavrentiev Ave. 5, Novosibirsk 630090, Russia

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 03-08-00384

Реферат: Orthorhombic lithium zinc molybdate was first chosen and explored as a candidate for double beta decay experiments with 100Mo. The phase equilibria in the system Li2MoO4–ZnMoO4 were reinvestigated, the intermediate compound Li2Zn2(MoO4)3 of the α-Cu3Fe4(VO4)6 (lyonsite) type was found to be nonstoichiometric: Li2−2xZn2+x(MoO4)3 (0≤x≤0.28) at 600 °C. The eutectic point corresponds to 650 °C and 23 mol% ZnMoO4, the peritectic point is at 885 °C and 67 mol% ZnMoO4. Single crystals of the compound were prepared by spontaneous crystallization from the melts and fluxes. In the structures of four Li2−2xZn2+x(MoO4)3 crystals (x=0; 0.03; 0.21; 0.23), the cationic sites in the face-shared octahedral columns were found to be partially filled and responsible for the compound nonstoichiometry. It was first showed that with increasing the x value and the number of vacancies in M3 site, the average M3–O distance grows and the lithium content in this site decreases almost linearly. Using the low-thermal-gradient Czochralski technique, optically homogeneous large crystals of lithium zinc molybdate were grown and their optical, luminescent and scintillating properties were explored.
Библиографическая ссылка: Solodovnikov S.F. , Solodovnikova Z.A. , Zolotova E.S. , Yudanova L.I. , Kardash T.Y. , Pavlyuk A.A. , Nadolinny V.A.
Revised Phase Diagram of Li2MoO4-ZnMoO4 System, Crystal Structure and Crystal Growth of Lithium Zinc Molybdate
Journal of Solid State Chemistry. 2009. V.182. N7. P.1935-1943. DOI: 10.1016/j.jssc.2009.04.036 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 17 мар. 2009 г.
Принята к публикации: 30 апр. 2009 г.
Опубликована online: 10 мая 2009 г.
Опубликована в печати: 1 июл. 2009 г.
Идентификаторы БД:
Web of science: WOS:000267717600049
Scopus: 2-s2.0-67649108886
РИНЦ: 13601689
Chemical Abstracts: 2009:781888
Chemical Abstracts (print): 151:323248
OpenAlex: W2062946031
Цитирование в БД:
БД Цитирований
Web of science 14
Scopus 14
РИНЦ 17
OpenAlex 13
Альметрики: