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Double Complex Salts [PdL4][RuNO(NO2)4OH] (L = NH3, Py) Synthesis, Structure and Preparation of Bimetallic Metastable Solid Solution Pd0.5Ru0.5 Научная публикация

Журнал Polyhedron
ISSN: 0277-5387
Вых. Данные Год: 2019, Том: 159, Страницы: 217-225 Страниц : 9 DOI: 10.1016/j.poly.2018.11.065
Ключевые слова Double complex salts; Thermolysis; Metastable solid solution; Palladium complex; Ruthenium complex
Авторы Kostin G.A. 1,2 , Plyusnin P.E. 1,2 , Filatov E.Yu. 1,2 , Kuratieva N.V. 1,2 , Vedyagin A.A. 3 , Kal’nyi D.B. 1,2
Организации
1 Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090, Russian Federation
2 Novosibirsk State University, Novosibirsk 630090, Russian Federation
3 Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russian Federation

Информация о финансировании (1)

1 Российский научный фонд 16-13-10192

Реферат: Two double complex salts containing [RuNO(NO2)4OH]2- anion and [PdL4]2+ cations (L = NH3, Py) were prepared and described by IR-spectroscopy, single crystal and powder XRD. The crystal structure of both compounds is composed by complex palladium cations and complex ruthenium anions. In case of [Pd(NH3)4][RuNO(NO2)4OH] cations and anions are bounded by hydrogen bonds between NH3 and NO2 ligands. The thermal decomposition of the salts was examined in inert and reductive atmospheres. Both the complexes decompose in several stages, first stage according to IR spectroscopy is comprised with the cleavage of OH group of anion, further decomposition undergoes with the removal on NH3 and NO2 ligands. In case of [Pd(NH3)4][RuNO(NO2)4OH] the final temperature of thermolysis in reductive atmosphere is 250-270°C and the final product corresponds to metastable Pd0.5Ru0.5 solid solution. The composition of metal solid solution was confirmed by XRD and EDX data. Electrochemical and catalytical properties of prepared solid solutions were examined.
Библиографическая ссылка: Kostin G.A. , Plyusnin P.E. , Filatov E.Y. , Kuratieva N.V. , Vedyagin A.A. , Kal’nyi D.B.
Double Complex Salts [PdL4][RuNO(NO2)4OH] (L = NH3, Py) Synthesis, Structure and Preparation of Bimetallic Metastable Solid Solution Pd0.5Ru0.5
Polyhedron. 2019. V.159. P.217-225. DOI: 10.1016/j.poly.2018.11.065 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 15 окт. 2018 г.
Принята к публикации: 30 нояб. 2018 г.
Опубликована online: 8 дек. 2018 г.
Опубликована в печати: 1 февр. 2019 г.
Идентификаторы БД:
Web of science: WOS:000458228000025
Scopus: 2-s2.0-85058366664
РИНЦ: 38640826
Chemical Abstracts: 2018:2529080
OpenAlex: W2905574791
Цитирование в БД:
БД Цитирований
Scopus 16
Web of science 15
РИНЦ 19
OpenAlex 18
Альметрики: