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High-Pressure Thermolysis of Sulfate Turpentine Научная публикация

Журнал The Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162
Вых. Данные Год: 2009, Том: 48, Номер: 2, Страницы: 139-145 Страниц : 7 DOI: 10.1016/j.supflu.2008.10.013
Ключевые слова High-pressure, Isomerization, Kinetics, Sulfate turpentine, Supercritical solvent, Thermodynamic, Thermolysis, Transition state theory
Авторы Yermakova A. 1 , Chibiryaev A.M. 2,3 , Kozhevnikov I.V. 1 , Anikeev V.I. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Prosp. Akad. Lavrent’eva 5, Novosibirsk 630090, Russian Federation
2 Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Prosp. Akad. Lavrent’eva 9, Novosibirsk 630090, Russian Federation
3 Department of Natural Sciences, Novosibirsk State University, ul. Pirogova 2, Novosibirsk 630090, Russian Federation

Реферат: Thermolysis of sulfate turpentine was studied in the pressure range of 40–280 atm. The conversion kinetics of main turpentine components (α-pinene, 3-carene) and their isomerization products (limonene, alloocimenes, pyronenes) was investigated and compared with the conversion kinetics of these compounds in supercritical ethanol. Thermodynamic parameters View the MathML source, View the MathML source and View the MathML source of the reversible reaction “α-pinene-[TS]” were estimated, the observed discrepancies being interpreted in the context of transition state theory. The thermolysis rate of α-pinene as a turpentine component was compared to that in a supercritical diluted solution of ethanol versus pressure. The rate of α-pinene conversion was shown to depend on the density of working medium.
Библиографическая ссылка: Yermakova A. , Chibiryaev A.M. , Kozhevnikov I.V. , Anikeev V.I.
High-Pressure Thermolysis of Sulfate Turpentine
The Journal of Supercritical Fluids. 2009. V.48. N2. P.139-145. DOI: 10.1016/j.supflu.2008.10.013 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 30 июн. 2008 г.
Принята к публикации: 14 окт. 2008 г.
Опубликована online: 31 окт. 2008 г.
Опубликована в печати: 1 мар. 2009 г.
Идентификаторы БД:
Web of science: WOS:000264250800006
Scopus: 2-s2.0-63749131467
РИНЦ: 13615017
Chemical Abstracts: 2009:222292
Chemical Abstracts (print): 151:472396
OpenAlex: W2088030751
Цитирование в БД:
БД Цитирований
Web of science 8
Scopus 10
РИНЦ 10
OpenAlex 9
Альметрики: