Peculiarities of Activation and Hydrogenation of Carbon Monoxide on Superdispersed Cobalt Particles Obtained by Decomposition of Co2(CO)8 on the Surface of Silica Full article
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5th International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis 15-19 Jul 1986 , Новосибирск |
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| Source | Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, USSR Compilation, CRC Press. 1986. 1170 c. ISBN 9789067640732. |
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| Output data | Year: 1986, Pages: 1065-1081 Pages count : 17 | ||
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Abstract:
The av. size of Co particles on hydrogenation catalysts obtained by thermal decompn. of Co2(CO)8 on Ti-hydride-treated SiO2 is 1-1.5 nm. Such finely dispersed Co has low affinity for adsorption of CO, thus having a low activity but a high selectivity for CO conversion to low-mol.-wt. alcs., mainly EtOH. Spectroscopic evidence (IR, NMR) suggests that the dissocn. of CO on catalysts with high Co dispersivity is slow; in contrast to the the catalyst on the Ti-hydride-SiO2 , the Co/unmodified SiO2 catalyst has relatively large (10-12 nm) Co particles. Even at ambient temp., CO dissocs. on its surface gives C deposits.
Cite:
Kuznetsov V.L.
, Lisitsyn A.S.
, Golovin A.V.
, Aleksandrov M.N.
, Ermakov Y.I.
Peculiarities of Activation and Hydrogenation of Carbon Monoxide on Superdispersed Cobalt Particles Obtained by Decomposition of Co2(CO)8 on the Surface of Silica
In compilation Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, USSR. – CRC Press., 1986. – C.1065-1081. – ISBN 9789067640732. ANCAN
Peculiarities of Activation and Hydrogenation of Carbon Monoxide on Superdispersed Cobalt Particles Obtained by Decomposition of Co2(CO)8 on the Surface of Silica
In compilation Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, USSR. – CRC Press., 1986. – C.1065-1081. – ISBN 9789067640732. ANCAN
Identifiers:
| Chemical Abstracts: | 1987:601676 |
| Chemical Abstracts (print): | 107:201676 |
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