EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation | Sciact - CRIS-system of Boreskov Institute of Catalysis

EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation Full article

Journal

Journal of the American Chemical Society
ISSN: 0002-7863 , E-ISSN: 1520-5126

Output data

Year: 2009, Volume: 131, Number: 31, Pages: 10798-10799 Pages count : 2 DOI: 10.1021/ja902659c

Tags

Catalysts; Electron resonance; Hydrocarbons; Hydrogen; Hydrogen peroxide; Iron compounds; Oxidation; Paramagnetic resonance; Quantum theory

Authors

Lyakin Oleg Y. ¹ , Bryliakov Konstantin P. ¹ , Britovsek George J. ² , Talzi Evgenii P. ¹

Affiliations

1	Siberian Branch of the Russian Academy of Sciences, Boreskov Institute of Catalysis, Novosibirsk 630090, Pr. Lavrentieva 5, Russia
2	Department of Chemistry, Imperial College London, London SW7 2AY, Exhibition Road, U.K.

Funding (2)

1	Russian Foundation for Basic Research	09-03-00087
2	Russian Foundation for Basic Research	06-03-32214

The key intermediate of a bioinspired iron catalyst for selective hydrocarbon oxidation based on hydrogen peroxide and an iron complex with a tetradentate aminopyridine ligand was trapped by EPR. On the basis of EPR and reactivity data this intermediate is tentatively proposed to be an oxoiron(V) complex.

Lyakin O.Y. , Bryliakov K.P. , Britovsek G.J. , Talzi E.P.
EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation
Journal of the American Chemical Society. 2009. V.131. N31. P.10798-10799. DOI: 10.1021/ja902659c WOS Scopus РИНЦ ANCAN PMID OpenAlex

Submitted:	Apr 3, 2009
Published online:	Jul 20, 2009
Published print:	Aug 12, 2009

Web of science:	WOS:000268806500002
Scopus:	2-s2.0-68249145924
Elibrary:	13612394
Chemical Abstracts:	2009:874456
Chemical Abstracts (print):	151:220660
PMID:	19722657
OpenAlex:	W1986513799

DB	Citing
Web of science	129
Scopus	138
Elibrary	138
OpenAlex	138