Radical Cations of Aromatic Molecules with High Ionization Potentials on the Surfaces of Oxide Catalysts: Formation, Properties, and Reactivity Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2009, Volume: 50, Number: 2, Pages: 314-324 Pages count : 11 DOI: 10.1134/S0023158409020232 | ||
| Tags | Zeolite; Radical Cation; Acceptor Site; Sulfated Zirconia; Aromatic Molecule | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 06-03-32712 |
Abstract:
The results obtained by the authors on the formation and properties of the radical cations of benzene and other molecules with high ionization potentials on the surfaces of ZSM-5 zeolites and sulfated zirconium dioxide are analyzed in this paper. It was found that radical cations of aromatic compounds can be obtained both by a thermal process and under illumination with visible light. Radical cations were found to be key intermediates in the low-temperature polycondensation of aromatic compounds on these catalysts. A possible mechanism of the formation of radical cations and the nature of the sites responsible for these processes are discussed.
Cite:
Bedilo A.F.
, Volodin A.M.
Radical Cations of Aromatic Molecules with High Ionization Potentials on the Surfaces of Oxide Catalysts: Formation, Properties, and Reactivity
Kinetics and Catalysis. 2009. V.50. N2. P.314-324. DOI: 10.1134/S0023158409020232 WOS Scopus РИНЦ ANCAN OpenAlex
Radical Cations of Aromatic Molecules with High Ionization Potentials on the Surfaces of Oxide Catalysts: Formation, Properties, and Reactivity
Kinetics and Catalysis. 2009. V.50. N2. P.314-324. DOI: 10.1134/S0023158409020232 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Бедило А.Ф.
, Володин А.М.
Катион-радикалы ароматических молекул с высоким потенциалом ионизации на поверхности оксидных катализаторов: образование, свойства и реакционная способность
Кинетика и катализ. 2009. Т.50. №2. С.332-343. РИНЦ
Катион-радикалы ароматических молекул с высоким потенциалом ионизации на поверхности оксидных катализаторов: образование, свойства и реакционная способность
Кинетика и катализ. 2009. Т.50. №2. С.332-343. РИНЦ
Dates:
| Submitted: | Mar 28, 2008 |
| Published print: | Mar 1, 2009 |
| Published online: | Apr 24, 2009 |
Identifiers:
| Web of science: | WOS:000265499100023 |
| Scopus: | 2-s2.0-65349192793 |
| Elibrary: | 13603861 |
| Chemical Abstracts: | 2009:496059 |
| Chemical Abstracts (print): | 151:100786 |
| OpenAlex: | W2020958624 |