Evaluation of the Acidic Properties of the B2O3–Al2O3 and Pt/B2O3–Al2O3 Systems by Spin Probe EPR Spectroscopy and Their Correlation with the Occurrence of the Joint Hydroisomerization of Heptane and Benzene Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2016, Volume: 57, Number: 4, Pages: 540-545 Pages count : 6 DOI: 10.1134/S0023158416040169 | ||||
| Tags | platinum catalysts, borate-containing aluminum oxide, TEMPO nitroxide radical, anthracene, Brønsted acid sites, hydroisomerization, heptane, benzene, spin probe EPR spectroscopy, solid-state 1H NMR spectroscopy | ||||
| Authors |
|
||||
| Affiliations |
|
Abstract:
The acidity of a series of borate-containing aluminum oxide samples with the concentrations of B2O3 from 0.9 to 27.5 wt % and Pt-containing catalysts obtained on their basis was studied by spin probe EPR spectroscopy. With the use of anthracene and the TEMPO nitroxide radical as probe molecules, it was established that an increase in the B2O3 content of the B2O3–Al2O3 and Pt/B2O3–Al2O3 systems leads to a symbatic increase in the number of medium-strength Brønsted acid sites (BASs). In this case, the yields of target hydroisomerization products (isoheptanes and methylcyclopentane) correlate with the number of BASs.
Cite:
Yurpalov V.L.
, Fedorova E.D.
, Drozdov V.A.
, Lavrenov A.V.
Evaluation of the Acidic Properties of the B2O3–Al2O3 and Pt/B2O3–Al2O3 Systems by Spin Probe EPR Spectroscopy and Their Correlation with the Occurrence of the Joint Hydroisomerization of Heptane and Benzene
Kinetics and Catalysis. 2016. V.57. N4. P.540-545. DOI: 10.1134/S0023158416040169 WOS Scopus РИНЦ AN OpenAlex
Evaluation of the Acidic Properties of the B2O3–Al2O3 and Pt/B2O3–Al2O3 Systems by Spin Probe EPR Spectroscopy and Their Correlation with the Occurrence of the Joint Hydroisomerization of Heptane and Benzene
Kinetics and Catalysis. 2016. V.57. N4. P.540-545. DOI: 10.1134/S0023158416040169 WOS Scopus РИНЦ AN OpenAlex
Original:
Юрпалов В.Л.
, Федорова Е.Д.
, Дроздов В.А.
, Лавренов А.В.
Оценка кислотных свойств систем B2O3–Al2O3 и Pt/B2O3–Al2O3 методом зондовой ЭПР-спектроскопии и их корреляция с протеканием совместной гидроизомеризации гептана и бензола
Кинетика и катализ. 2016. Т.57. №4. С.548-553. DOI: 10.7868/s0453881116040183 РИНЦ OpenAlex
Оценка кислотных свойств систем B2O3–Al2O3 и Pt/B2O3–Al2O3 методом зондовой ЭПР-спектроскопии и их корреляция с протеканием совместной гидроизомеризации гептана и бензола
Кинетика и катализ. 2016. Т.57. №4. С.548-553. DOI: 10.7868/s0453881116040183 РИНЦ OpenAlex
Dates:
| Submitted: | Sep 25, 2015 |
| Published print: | Jul 1, 2016 |
| Published online: | Jul 31, 2016 |
Identifiers:
| Web of science: | WOS:000381257800017 |
| Scopus: | 2-s2.0-84980351588 |
| Elibrary: | 27121885 |
| Chemical Abstracts: | 2016:1256234 |
| OpenAlex: | W2476674823 |