Palladium Hydrogenation Catalyst Based on a Porous Carbon Material Obtained upon the Dehydrochlorination of a Chloro Polymer Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2016, Volume: 57, Number: 2, Pages: 229-233 Pages count : 5 DOI: 10.1134/s0023158416020063 | ||||||||
| Tags | chlorinated PVC; carbon supports; palladium catalysts; nitrobenzene hydrogenation; chlorobenzene hydrodechlorination | ||||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 14-33-00018 (114123040010) |
Abstract:
The applicability of a porous carbon material obtained as a result of the “chemical” dehydrochlorination of chlorinated polyvinyl chloride as a support for palladium hydrogenation catalysts was demonstrated. The efficiency of the catalyst was evaluated in the liquid-phase reactions of nitrobenzene hydrogenation and chlorobenzene hydrodechlorination. Although the specific activity of the catalyst was lower by a factor of 3–4 than that of the samples based on Sibunit and carbon nanotubes, the complete conversion of the initial compounds with the selective formation of end products under mild conditions was achieved at a relatively low palladium content (1.5%).
Cite:
Mironenko R.M.
, Belskaya O.B.
, Solodovnichenko V.S.
, Gulyaeva T.I.
, Kryazhev Y.G.
, Likholobov V.A.
Palladium Hydrogenation Catalyst Based on a Porous Carbon Material Obtained upon the Dehydrochlorination of a Chloro Polymer
Kinetics and Catalysis. 2016. V.57. N2. P.229-233. DOI: 10.1134/s0023158416020063 WOS Scopus РИНЦ AN OpenAlex
Palladium Hydrogenation Catalyst Based on a Porous Carbon Material Obtained upon the Dehydrochlorination of a Chloro Polymer
Kinetics and Catalysis. 2016. V.57. N2. P.229-233. DOI: 10.1134/s0023158416020063 WOS Scopus РИНЦ AN OpenAlex
Original:
Мироненко Р.М.
, Бельская О.Б.
, Солодовниченко В.С.
, Гуляева Т.И.
, Кряжев Ю.Г.
, Лихолобов В.А.
Палладиевый катализатор гидрирования на основе пористого углеродного материала, полученного при дегидрохлорировании хлорполимера
Кинетика и катализ. 2016. Т.57. №2. С.223-227. DOI: 10.7868/S0453881116020064 РИНЦ OpenAlex
Палладиевый катализатор гидрирования на основе пористого углеродного материала, полученного при дегидрохлорировании хлорполимера
Кинетика и катализ. 2016. Т.57. №2. С.223-227. DOI: 10.7868/S0453881116020064 РИНЦ OpenAlex
Dates:
| Submitted: | Jul 1, 2015 |
| Published print: | Mar 1, 2016 |
| Published online: | May 12, 2016 |
Identifiers:
| Web of science: | WOS:000376094000014 |
| Scopus: | 2-s2.0-84979527758 |
| Elibrary: | 27095540 |
| Chemical Abstracts: | 2016:773140 |
| OpenAlex: | W2348206091 |